Long-term contamination in a recovered area affected by a mining spill

• Published in: The Science of the total environment 2015-05, Vol.514, p.219-223
• Main Authors: Martin Peinado, FJ, Romero-Freire, A, Garcia Fernandez, I, Sierra Aragon, M, Ortiz-Bernad, I, Simon Torres, M
• Format: Article
• Language: English
• Subjects: Arsenic; Aznalcóllar spill; Environmental Monitoring; Environmental Pollution - statistics & numerical data; Heavy metals; Metals, Heavy - analysis; Mining; Soil - chemistry; Soil Pollutants - analysis; Soil remediation; Spain
• ISSN: 0048-9697; 1879-1026
• DOI: 10.1016/j.scitotenv.2015.01.102

Soil pollution from the spill of Aznalcóllar mine (S Spain) was monitored by analysing polluted soils in 1998, 1999, and 2004. Following the methodology used in previous studies, in 2013 we conducted a new sampling and analysis of the soils affected by the spill and the data were compared with those of 2004. The results confirm that the pH tended to rise and concentration of pollutants tended to diminish over time. In 2013, the total concentration of pollutants was within the normal range for uncontaminated soils and close to the background concentration of the soils prior to the spill; while the soluble concentration of pollutants was clearly below the toxic level. These results indicate that remediation measures implemented have been effective. However, the removal of tailings (first remediation measure applied) was deficient and in many places the tailings were mixed with the soil. The high concentration of sulphides and metal(loid)s in the tailings gave rise to spots with very acidic and highly polluted soils devoid of vegetation. In 2013, fifteen years after the spill, these spots of bare soils remain a major source of pollution from which pollutants are scattered through the solid and liquid phases of runoff water, requiring action to immobilize pollutants and encourage the restoration of vegetation on these soils. In this type of pollution in a Mediterranean environment, the complete removal of tailings is more important than the speed at which they are removed. •15 years after the accident around 7% of the affected soils remain unrecovered.•Soils with acidic pH and high As and Pb total concentrations are still detected.•Soil remediation actions are required to remove these sources of pollution.