Synthesis and characterization of Ag3PO4 immobilized with graphene oxide (GO) for enhanced photocatalytic activity and stability over 2,4-dichlorophenol under visible light irradiation

• Published in: Journal of hazardous materials 2015-07, Vol.292, p.9-18
• Main Authors: Chen, Xiao-juan, Dai, You-zhi, Wang, Xing-yan, Guo, Jing, Liu, Tan-hua, Li, Fen-fang
• Format: Article
• Language: English
• Subjects: 2,4-Dichlorophenol; Ag3PO4–GO; Catalysis; Chlorophenols - chemistry; Degradation; Degradation intermediates; Free radicals; Graphene; Graphite - chemistry; High performance liquid chromatography; Light; Microscopy, Electron, Scanning; Microscopy, Electron, Transmission; Oxides; Oxides - chemistry; Phosphates - chemistry; Photocatalysis; Photocatalysts; Photocatalytic mechanism; Photochemical Processes; Silver Compounds - chemistry; Spectrometry, X-Ray Emission; Stability; Visible light photocatalysis
• ISSN: 0304-3894; 1873-3336
• DOI: 10.1016/j.jhazmat.2015.01.032

[Display omitted] •A series of Ag3PO4–GO photocatalysts with different GO content were prepared.•Photocatalytic activity of Ag3PO4–GO to 2,4-DCP increased with GO content increasing.•GO played significant role in the enhanced photocatalytic activity and stability.•Degradation pathway of 2,4-DCP and photocatalytic mechanism of Ag3PO4–GO were proposed. A series of visible-light responsive photocatalysts prepared using Ag3PO4 immobilized with graphene oxide (GO) with varying GO content were obtained by an electrostatically driven method, and 2,4-dichlorophenol (2,4-DCP) was used to evaluate the performance of the photocatalysts. The composites exhibited superior photocatalytic activity and stability compared with pure Ag3PO4. When the content of GO was 5%, the degradation efficiency of 2,4-DCP could reach 98.95%, and 55.91% of the total organic (TOC) content was removed within 60min irradiation. Meanwhile, the efficiency of 91.77% was achieved for 2,4-DCP degradation even after four times of recycling in the photocatalysis/Ag3PO4–GO (5%) system. Reactive species of O2−, OH and h+ were considered as the main participants for oxidizing 2,4-DCP, as confirmed by the free radical capture experiments. And some organic intermediates including 4-chlorophenol (4-CP), hydroquinone (HQ), benzoquinone (BZQ), 2-chlorohydroquinone and hydroxyhydroquinone (HHQ) were detected by comparison with the standard retention times from the high performance liquid chromatography (HPLC). In short, the enhanced photocatalytic property of Ag3PO4–GO was closely related to the strong absorption ability of GO relative to 2,4-DCP, the effective separation of photogenerated electron–hole pairs, and the excellent electron capture capability of GO.