Biodiesel production from used cooking oil by two-step heterogeneous catalyzed process

• Published in: Bioresource technology 2012-09, Vol.119, p.306-311
• Main Authors: Srilatha, K., Prabhavathi Devi, B.L.A., Lingaiah, N., Prasad, R.B.N., Sai Prasad, P.S.
• Format: Article
• Language: English
• Subjects: Biodiesel; Biofuels; Catalysis; Catalysts; Cooking; Esterification; Fatty acids; Fatty Acids, Nonesterified - chemistry; Heating; Methanol - chemistry; Methyl alcohol; Oils - chemistry; Solid catalyst; Transesterification; Two-step method; Zeolites - chemistry; Zinc oxide
• ISSN: 0960-8524; 1873-2976
• DOI: 10.1016/j.biortech.2012.04.098

[Display omitted] ▸ An economical and eco-friendly two-step heterogeneously catalyzed process for biodiesel production is presented. ▸ The process is applicable to oil feedstocks containing high free fatty acids. ▸ Very cheap used cooking oil is taken as feedstock and high yields of biodiesel are achieved. ▸ The solid catalysts used are highly active and reusable for both esterification and transesterification reactions. The present study demonstrates the production of biodiesel from used cooking oil containing high free fatty acid by a two-step heterogeneously catalyzed process. The free fatty acids were first esterified with methanol using a 25wt.% TPA/Nb2O5 catalyst followed by transesterification of the oil with methanol over ZnO/Na-Y zeolite catalyst. The catalysts were characterized by XRD, FT-IR, BET surface area and CO2-TPD. In the case of transesterification the effect of reaction parameters, such as catalyst concentration, methanol to oil molar ratio and reaction temperature, on the yield of ester were investigated. The catalyst with 20wt.% ZnO loading on Na-Y exhibited the highest activity among the others. Both the solid acid and base catalysts were found to be reusable for several times indicating their efficacy in the two-step process.