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Syntheses, characterization, and urease inhibition of oxidovanadium(V) complexes with tridentate hydrazone and bidentate benzohydroxamate ligands

New oxidovanadium(V) complexes, [VOL 1 (bzh))]·H 2 O (1) and [VOL 2 (bzh))] (2), were prepared by the reaction of [VO(acac) 2 ] (where acac = acetylacetonate) and benzohydroxamic acid (Hbzh) with N′-(5-bromo-2-hydroxybenzylidene)-3-methylbenzohydrazide (H 2 L 1 ) and N′-(5-bromo-2-hydroxybenzylidene...

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Bibliographic Details
Published in:Journal of coordination chemistry 2014-07, Vol.67 (14), p.2415-2424
Main Authors: Qian, Shao-Song, You, Zhonglu, Huo, Yang, Ye, Yu-Ting, Cheng, Xiao-Shan, Zhu, Hai-Liang
Format: Article
Language:English
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Summary:New oxidovanadium(V) complexes, [VOL 1 (bzh))]·H 2 O (1) and [VOL 2 (bzh))] (2), were prepared by the reaction of [VO(acac) 2 ] (where acac = acetylacetonate) and benzohydroxamic acid (Hbzh) with N′-(5-bromo-2-hydroxybenzylidene)-3-methylbenzohydrazide (H 2 L 1 ) and N′-(5-bromo-2-hydroxybenzylidene)-4-methylbenzohydrazide (H 2 L 2 ), respectively, in methanol. Structures of the complexes were determined by elemental analysis, infrared and UV-vis spectra. Single crystal structures of the complexes were determined by X-ray diffraction. Vanadiums have octahedral coordination. Thermal stability and the inhibition of urease of the complexes were studied.
ISSN:0095-8972
1029-0389
DOI:10.1080/00958972.2014.944176