Synthesis, Crystal Structure, and Biological Property of a Novel Dinuclear Copper(II) Complex

The reaction of 2-acetylpyridine, cyclohexylamine and copper(II) perchlorate in methanol resulted in the dinuclear copper(II) complex [Cu 2 L 2 ]·2ClO 4 , where L is the monoanionic form of 1-methoxy-1,3-dipyridin-2-ylbutane-1,3-diol. The complex was characterized by elemental analysis and IR spectr...

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Published in:Synthesis and reactivity in inorganic, metal-organic, and nano-metal chemistry metal-organic, and nano-metal chemistry, 2016-02, Vol.46 (2), p.185-188
Main Authors: Li, Chao, Meng, Xu-Feng, Li, Wei-Ning, Zhou, Xin, Ma, Jing-Jun
Format: Article
Language:English
Subjects:
antibacterial activity
Bacteria
Biological
copper complex
crystal structure
dinuclear complex
Inversions
Iridium
Methyl alcohol
MICROSTRUCTURES
Nanostructure
Perchlorates
Synthesis (chemistry)
thermal behavior
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creator Li, Chao
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description The reaction of 2-acetylpyridine, cyclohexylamine and copper(II) perchlorate in methanol resulted in the dinuclear copper(II) complex [Cu 2 L 2 ]·2ClO 4 , where L is the monoanionic form of 1-methoxy-1,3-dipyridin-2-ylbutane-1,3-diol. The complex was characterized by elemental analysis and IR spectroscopic method in the solid state. Single-crystal X-ray analysis was performed, which indicated that the complex possesses a crystallographic inversion center symmetry. The Cu atom in the complex is in a square pyramidal geometry. Thermal behavior and biological property on the bacteria strains B. subtilis, E. coli, and S. aureus of the complex were studied.
doi_str_mv 10.1080/15533174.2014.963238
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subjects antibacterial activity
Bacteria
Biological
copper complex
crystal structure
dinuclear complex
Inversions
Iridium
Methyl alcohol
MICROSTRUCTURES
Nanostructure
Perchlorates
Synthesis (chemistry)
thermal behavior
title Synthesis, Crystal Structure, and Biological Property of a Novel Dinuclear Copper(II) Complex
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