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Ultrasound mediation for one-pot sonosynthesis and deposition of magnetite nanoparticles on cotton/polyester fabric as a novel magnetic, photocatalytic, sonocatalytic, antibacterial and antifungal textile

[Display omitted] •Ultrasound mediation in oxidation of Fe2+ to Fe3+ via hydroxyl radicals.•Magnetite nanoparticles formation using only one iron rich precursor.•Sonosynthesis and sonofabrication of Fe3O4 nanoparticles on cotton/polyester fabric.•Simultaneous magnetic, photocatalytic, sonocatalytic,...

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Published in:Ultrasonics sonochemistry 2016-07, Vol.31, p.257-266
Main Authors: Rastgoo, Madine, Montazer, Majid, Malek, Reza M.A., Harifi, Tina, Mahmoudi Rad, Mahnaz
Format: Article
Language:English
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Summary:[Display omitted] •Ultrasound mediation in oxidation of Fe2+ to Fe3+ via hydroxyl radicals.•Magnetite nanoparticles formation using only one iron rich precursor.•Sonosynthesis and sonofabrication of Fe3O4 nanoparticles on cotton/polyester fabric.•Simultaneous magnetic, photocatalytic, sonocatalytic, antibacterial and antifungal activities.•Enhanced tensile strength of the treated fabrics. A magnetic cotton/polyester fabric with photocatalytic, sonocatalytic, antibacterial and antifungal activities was successfully prepared through in-situ sonosynthesis method under ultrasound irradiation. The process involved the oxidation of Fe2+ to Fe3+ via hydroxyl radicals generated through bubbles collapse in ultrasonic bath. The treated samples were analyzed by X-ray diffraction, field emission scanning electron microscopy, energy dispersive X-ray spectroscopy and vibrating sample magnetometry. Photocatalytic and sonocatalytic activities of magnetite treated fabrics were also evaluated toward Reactive Blue 2 decoloration under sunlight and ultrasound irradiation. Central composite design based on response surface methodology was applied to study the influence of iron precursor, pH and surfactant concentration to obtain appropriate amount for the best magnetism. Findings suggested the potential of one-pot sonochemical method to synthesize and fabricate Fe3O4 nanoparticles on cotton/polyester fabric possessing appropriate saturation magnetization, 95% antibacterial efficiency against Staphylococcus aureus and 99% antifungal effect against Candida albicans, 87% and 70% dye photocatalytic and sonocatalytic decoloration along with enhanced mechanical properties using only one iron rich precursor at low temperature.
ISSN:1350-4177
1873-2828
DOI:10.1016/j.ultsonch.2016.01.008