An effective surface modification of carbon fiber for improving the interfacial adhesion of polypropylene composites

• Published in: Materials & design 2015-12, Vol.88, p.810-819
• Main Authors: Liu, Yuan, Zhang, Xue, Song, Chenchen, Zhang, Yuanyuan, Fang, Yichao, Yang, Bin, Wang, Xinling
• Format: Article
• Language: English
• Subjects: Adhesion; Carbon fiber; Interfacial shear strength; Maleic anhydride grafted PP; Mechanical analysis; Modulus of rupture in bending; Morphology; Polypropylenes; Surface treatment; Terpolymers; Thermoplastic composite; X-ray photoelectron spectroscopy
• ISSN: 0264-1275; 1873-4197
• DOI: 10.1016/j.matdes.2015.09.100

A simple and effective modification for carbon fiber (CF) was presented in our work. CF was coated with ethylene–methyl acrylate–glycidyl methacrylate (E–MA–GMA) terpolymer through solution dipping. A uniform layer of 2.0wt.% E–MA–GMA was confirmed on CF by IR, TGA and SEM. XPS showed that surface oxygen-containing functional groups were obviously increased after modification, which were advantageous to promote the reactivity of CFs. The treatment turned out to be helpful in enhancing the interfacial adhesion by micro-droplet experiment and the interfacial shear strength was 157% higher. The physical properties of PP/mCF composites were improved by static and dynamic mechanical analysis and the improvement was more noteworthy when maleic anhydride grafted PP (MAPP) was added to the matrix, which was consistent with the fracture morphology. The ultimate flexural strength, impact energy and tensile strength were increased by 139.3%, 233.9% and 126.1%. Besides, the mechanical performance of PP composites with 0–30wt.% CFs were all significantly enhanced by CF surface treatment in combination with MAPP modification. We believed that the excellent performance was not caused by fiber length or crystallinity, it was mainly due to the superior interfacial interaction by intermolecular chain entanglement, as well as chemical reaction between E–MA–GMA and MAPP. [Display omitted] •CFs were modified by solution dipping method using E–MA–GMA.•CF surface treatment and MAPP addition notably increased the interfacial interaction.•The improved interfacial adhesion led to superior mechanical performance.•The interfacial enhancement mechanism was discussed.