Porphyrin-POSS Molecular Hybrids

Porphyrin‐POSS hybrid: Porphyrin‐POSS molecular hybrid composites (see scheme; POSS = polyhedral oligomeric silsesquioxanes) were synthesized and structurally characterized, allowing the realization of truly homogenous dispersion of basic functional building blocks between organic and inorganic comp...

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Bibliographic Details
Published in:Chemistry : a European journal 2013-09, Vol.19 (38), p.12613-12618
Main Authors: Sun, Junshan, Chen, Yanli, Zhao, Luyang, Chen, Yuting, Qi, Dongdong, Choi, Kyung-Min, Shin, Dong-Soo, Jiang, Jianzhuang
Format: Article
Language:English
Subjects:
Agglomeration
Chemistry
Dispersions
fluorescence
Hybrid composites
molecular hybrid
Optical properties
Optimization
Polyhedral oligomeric silsesquioxane
polyhedral oligomeric silsesquioxanes
porphyrin
structure elucidation
Zinc compounds
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Summary:Porphyrin‐POSS hybrid: Porphyrin‐POSS molecular hybrid composites (see scheme; POSS = polyhedral oligomeric silsesquioxanes) were synthesized and structurally characterized, allowing the realization of truly homogenous dispersion of basic functional building blocks between organic and inorganic components at the molecular level. These materials allow the optimization of aggregation/association behavior and thus the functional optical properties of the porphyrinato zinc compounds.
ISSN:0947-6539
1521-3765
DOI:10.1002/chem.201301875