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Synthesis of highly crystalline copper phthalocyanine needles by solvothermal method

As an important organic semiconductor, copper phthalocyanine has been widely used in various photo/electronic devices. Until now, the one-step synthesis of copper phthalocyanine micro/nano-crystals is mainly limited to the high cost physical vapor deposition technology. Herein, for the first time, w...

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Bibliographic Details
Published in:Materials letters 2016-01, Vol.163, p.61-64
Main Authors: Ge, Suxiang, Zhang, Yange, Huang, Baojun, Huang, Shuiping, Tie, Weiwei, Lei, Yan, He, Qin, Tu, Guangliang, Qin, Qingqing, Niu, Sasa, Li, Mingtian, Li, Dapeng, Zheng, Zhi
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Language:English
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Summary:As an important organic semiconductor, copper phthalocyanine has been widely used in various photo/electronic devices. Until now, the one-step synthesis of copper phthalocyanine micro/nano-crystals is mainly limited to the high cost physical vapor deposition technology. Herein, for the first time, we proposed a green and low-cost solvothermal method for direct synthesis of highly crystalline copper phthalocyanine needles in nontoxic anhydrous ethanol medium at 190°C. The purification of the as prepared copper phthalocyanine needles just required washing unreacted reactants with ethanol. The structures and morphologies of the copper phthalocyanine needles were characterized by Raman spectroscopy, X-ray powder diffractometor, and scanning electronic microscopy, respectively. Moreover, the thermal and photoelectronic performances were investigated preliminarily. [Display omitted] •Needle-like CuPc crystals was synthesized via a solvothermal reaction.•Anhydrous ethanol was used as the reaction medium.•The green, facile and low-cost synthesis route of CuPc crystals was proposed.
ISSN:0167-577X
1873-4979
DOI:10.1016/j.matlet.2015.10.020