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Effect of nanocomposite structure on the thermoelectric properties of 0.7-at% Bi-doped Mg2Si nanocomposite
Nanocomposites offer a promising approach to the incorporation of nanostructured constituents into bulk thermo- electric materials. The 0.7-at% Bi-doped Mg2Si nanocomposites are prepared by spark plasma sintering of the mixture of nanoscale and microsized 0.7-at% Bi-doped Mg2Si powders. Microstructu...
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Published in: | Chinese physics B 2011-10, Vol.20 (10), p.355-361 |
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Main Authors: | , , |
Format: | Article |
Language: | English |
Subjects: | |
Online Access: | Get full text |
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Summary: | Nanocomposites offer a promising approach to the incorporation of nanostructured constituents into bulk thermo- electric materials. The 0.7-at% Bi-doped Mg2Si nanocomposites are prepared by spark plasma sintering of the mixture of nanoscale and microsized 0.7-at% Bi-doped Mg2Si powders. Microstructure analysis shows that the bulk material is composed of nano- and micrograins. Although the nanograin hinders electrical conduction, the nanocomposite struc- ture is more helpful to reduce thermal conductivity and increase the Seebeck coefficient, hence improving thermoelectric performance. A dimensionless figure of merit of 0.8 is obtained for the 0.7-at% Bi-doped Mg2Si nanocomposite with 50-wt % nanopowder, which is about twice larger than that of the sample without nanopowder. |
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ISSN: | 1674-1056 2058-3834 |
DOI: | 10.1088/1674-1056/20/10/106202 |