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Effect of nanocomposite structure on the thermoelectric properties of 0.7-at% Bi-doped Mg2Si nanocomposite

Nanocomposites offer a promising approach to the incorporation of nanostructured constituents into bulk thermo- electric materials. The 0.7-at% Bi-doped Mg2Si nanocomposites are prepared by spark plasma sintering of the mixture of nanoscale and microsized 0.7-at% Bi-doped Mg2Si powders. Microstructu...

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Published in:Chinese physics B 2011-10, Vol.20 (10), p.355-361
Main Authors: Yang, Mei-Jun (梅君 杨), Shen, Qiang (强沈), Zhang, Lian-Meng (联盟 张)
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container_issue 10
container_start_page 355
container_title Chinese physics B
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creator Yang, Mei-Jun (梅君 杨)
Shen, Qiang (强沈)
Zhang, Lian-Meng (联盟 张)
description Nanocomposites offer a promising approach to the incorporation of nanostructured constituents into bulk thermo- electric materials. The 0.7-at% Bi-doped Mg2Si nanocomposites are prepared by spark plasma sintering of the mixture of nanoscale and microsized 0.7-at% Bi-doped Mg2Si powders. Microstructure analysis shows that the bulk material is composed of nano- and micrograins. Although the nanograin hinders electrical conduction, the nanocomposite struc- ture is more helpful to reduce thermal conductivity and increase the Seebeck coefficient, hence improving thermoelectric performance. A dimensionless figure of merit of 0.8 is obtained for the 0.7-at% Bi-doped Mg2Si nanocomposite with 50-wt % nanopowder, which is about twice larger than that of the sample without nanopowder.
doi_str_mv 10.1088/1674-1056/20/10/106202
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subjects Intermetallics
Magnesium compounds
Mg2Si
Nanocomposites
Nanomaterials
Nanostructure
Seebeck系数
Semiconductors
Silicides
Thermoelectricity
双掺杂
复合材料结构
微观结构分析
放电等离子烧结
热电性能
纳米复合材料
title Effect of nanocomposite structure on the thermoelectric properties of 0.7-at% Bi-doped Mg2Si nanocomposite
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