Spin-dependent deprotonation induced giant magnetocurrent in electrochemical cells

A giant magnetocurrent (>100%) is observed in the electrochemical system based on tertiary amines at room temperature. This giant magnetocurrent is ascribed to spin-dependent deprotonation during the oxidation of tertiary amines. This presents a new approach of using spin-dependent deprotonation...

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Bibliographic Details
Published in:Physical chemistry chemical physics : PCCP 2016-04, Vol.18 (15), p.9897-991
Main Authors: Pan, Haiping, Shen, Yan, Duan, Jiashun, Lu, Kai, Hu, Bin
Format: Article
Language:English
Subjects:
Amines
Chemical reactions
Electrochemical cells
Oxidation
Physical chemistry
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Summary:A giant magnetocurrent (>100%) is observed in the electrochemical system based on tertiary amines at room temperature. This giant magnetocurrent is ascribed to spin-dependent deprotonation during the oxidation of tertiary amines. This presents a new approach of using spin-dependent deprotonation to generate giant magnetocurrent in electrochemical reactions. Spin-dependent deprotonation can be used as a new mechanism to generate giant magnetocurrent based on non-magnetic electrochemical systems.
ISSN:1463-9076
1463-9084
DOI:10.1039/c6cp00987e