A bifunctional chiral [2]catenane based on 1,1-binaphthyl-phosphates

A novel [2]catenane was synthesised by ring-closing metathesis from a Ca-bisphosphate template. The resulting interlocked structure features two chiral 1,1-binaphthyl-phosphates, leading to a bifunctional catenane structure. Initial binding studies point at the applicability of such mechanically int...

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Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2016-05, Vol.52 (35), p.5977-598
Main Authors: Mitra, R, Thiele, M, Octa-Smolin, F, Letzel, M. C, Niemeyer, J
Format: Article
Language:English
Subjects:
Binding
Decomposition reactions
Metathesis
Receptors
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Summary:A novel [2]catenane was synthesised by ring-closing metathesis from a Ca-bisphosphate template. The resulting interlocked structure features two chiral 1,1-binaphthyl-phosphates, leading to a bifunctional catenane structure. Initial binding studies point at the applicability of such mechanically interlocked bisphosphates as artificial receptors for dicationic guest molecules. A novel [2]catenane, featuring two chiral 1,1-binaphthyl-phosphates, was synthesised by ring-closing metathesis. The resulting bifunctional catenane was used as a chiral interlocked host for the binding of dicationic guest molecules.
ISSN:1359-7345
1364-548X
DOI:10.1039/c6cc01980c