Effect of composition and temperature on conductive and sensing properties of CeO2+In2O3 nanocomposite films

• Published in: Sensors and actuators. B, Chemical Chemical, 2015-03, Vol.209, p.562-569
• Main Authors: Trakhtenberg, L.I., Gerasimov, G.N., Gromov, V.F., Belysheva, T.V., Ilegbusi, O.J.
• Format: Article
• Language: English
• Subjects: Ambience; Chemical gas sensor; Chemisorption; Concentration (composition); Conductometric sensor; Enrichment; Indium oxides; Mixed metal-oxide film; Nanocomposite sensor films; Nanostructure; Sensor mechanism; Sensors; X-ray photoelectron spectroscopy
• ISSN: 0925-4005; 1873-3077
• DOI: 10.1016/j.snb.2014.12.022

The sensory response of nanostructured In2O3+CeO2 composite films to hydrogen and carbon monoxide in air ambience is investigated for varying film composition and temperature ranging from 280°C to 520°C. The temperature dependence of the sensor response S (S=R0/R, where R0 and R are respectively the film resistance in pure air and air containing the sample gas), exhibits the trend typical of such sensors, specifically, curves with maximum Smax at a certain temperature Tmax. The values of Smax, characterizing the sensor response of the films significantly increase when a small amount of CeO2 is added to In2O3. Addition of CeO2 to In2O3 also results in a decrease in Tmax. The measured XPS spectra show that at low CeO2 composition, the composite film structure is characterized by clusters with a high concentration of oxygen vacancies, which increase the chemisorption of reagents and oxygen. The maximum sensor response is observed in In2O3+CeO2 composite films containing 3–10wt.% CeO2. Further enrichment of the composite with CeO2 produces a sharp decrease in sensor response, which at 40wt.% CeO2 is less than the response of pure In2O3. The response mechanism in the In2O3+CeO2 composite is also investigated, considering the promotion of sensory reactions by small CeO2 nanoclusters located on the surface of the In2O3 nanocrystals.