Synthesis of green TiO2/ZnO/CdS hybrid nano-catalyst for efficient light harvesting using an elegant pulsed laser ablation in liquids method

• Published in: Applied surface science 2015-12, Vol.357, p.2217-2222
• Main Authors: Gondal, M.A., Ilyas, A.M., Fasasi, T.A., Dastageer, M.A., Seddigi, Z.S., Qahtan, T.F., Faiz, M., Khattak, G.D.
• Format: Article
• Language: English
• Subjects: Absorption spectra; Cadmium sulfides; Efficient light harvesting photocatalyst; Harvesting; Laser ablation; Liquids; Nanocomposite (TiO2/ZnO/CdS); Pulsed laser ablation in liquids; Pulsed lasers; Quantum dots; Titanium dioxide; Zinc oxide
• ISSN: 0169-4332; 1873-5584
• DOI: 10.1016/j.apsusc.2015.09.213

•Facile strategy for synthesis of green catalyst (TiO2/ZnO/CdS) was developed.•Clean synthesis of green catalyst was done using pulsed laser ablation in liquids.•Synthesized composite size ranges between 10 and 40nm confirmed by HRTEM studies.•Enhanced improvement was noticed in the carriers transport in the visible region.•Visible region absorption opens door to many applications for solar energy harvesting. The main limitation on the applications of TiO2 as a photocatalyst is its large band gap (3.2eV) which limits its absorption only to the ultraviolet region of the solar spectrum. To overcome this problem, a facile strategy for clean synthesis of a nanocomposite green catalyst of zinc oxide (ZnO), titanium dioxide (TiO2) and cadmium sulphide (CdS) was developed using pulsed laser ablation in liquids (PLAL) technique for the first time to the best of our knowledge. The main aim of addition of ZnO is to reduce the electron–hole recombination in the TiO2 while CdS is used to increase the light harvesting efficiency of TiO2 in the visible spectral region. The absorption spectrum of the TiO2/ZnO/CdS composite obtained from the UV–vis spectrophotometer exhibits strong absorption in the visible region as compared to the pure TiO2 whose absorption band lies around 380nm which is in the UV-region. The morphology of the composite quantum dots was also investigated using high resolution TEM technique which shows that the synthesized composite size ranges between 10 and 40nm. These nanocomposites have demosntarted noticible improvement in the carriers transport in the visible region which could enhance its efficiency for many applications in the visible region especially for energy harvesting using solar radiations.