New insights into alkylammonium-functionalized clinoptilolite and Na-P1 zeolite: Structural and textural features

•With increasing carbon chain length in the surfactant the molecules adopt a more disorder structure.•FTIR could be used for the determination of modification efficiency in organo-zeolites.•The salt detachment begins through ammonium head-group decomposition.•Modification process reduces the specifi...

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Bibliographic Details
Published in:Applied surface science 2016-01, Vol.361, p.242-250
Main Authors: Muir, Barbara, Matusik, Jakub, Bajda, Tomasz
Format: Article
Language:English
Subjects:
Carbon
Chains
Hydrophobicity
Organo-zeolite
Porosity
Quaternary ammonium salts
Surface layer
Surface modified zeolite
Surfactants
Synthetic zeolite
Texture
Zeolites
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Summary:•With increasing carbon chain length in the surfactant the molecules adopt a more disorder structure.•FTIR could be used for the determination of modification efficiency in organo-zeolites.•The salt detachment begins through ammonium head-group decomposition.•Modification process reduces the specific surface area and porosity of the material.•With an increasing carbon chain length the textural parameters decrease. The area of zeolites’ application could be expanded by utilizing their surfaces. Zeolites are frequently modified to increase their hydrophobicity and to generate the negative charge of the surface. The main objective of the study was to investigate and compare the features of natural clinoptilolite and synthetic zeolite Na-P1 modified by selected surfactants involving quaternary ammonium salts. The FTIR study indicates that with increasing carbon chain length in the surfactant attached to the zeolites surface the molecules adopt a more disordered structure. FTIR was also used to determine the efficiency of surface modification. Thermal analysis revealed that the presence of surfactant results in additional exothermic effects associated with the breaking of electrostatic bonds between zeolites and surfactants. The mass losses are in line with ECEC and CHN data. The textural study indicates that the synthetic zeolite Na-P1 has better sorption properties than natural clinoptilolite. The modification process always reduces the SBET and porosity of the material. With an increasing carbon chain length of surfactants all the texture parameters decrease.
ISSN:0169-4332
1873-5584
DOI:10.1016/j.apsusc.2015.11.116