Nanoscale morphology of Ni50Ti45Cu5 nanoglass

• Published in: Materials characterization 2016-03, Vol.113, p.26-33
• Main Authors: Śniadecki, Z., Wang, D., Ivanisenko, Yu, Chakravadhanula, V.S.K., Kübel, C., Hahn, H., Gleiter, H.
• Format: Article
• Language: English
• Subjects: Chemical segregation; Density; Formations; Glassy; Grain boundaries; Intermetallic compounds; Magnetron sputtering; Morphology; Nanocolumn; Nanoglass; Nanostructure; Surface diffusion; Transmission electron microscopy
• ISSN: 1044-5803; 1873-4189
• DOI: 10.1016/j.matchar.2015.12.025

Nanoglasses are noncrystalline solids with a granular nano-/microstructure. In contrast to their nanocrystalline analogs, typically constituted of grains and grain boundaries, nanoglasses consist of glassy regions with a structure corresponding to melt-quenched glasses and amorphous interfaces characterized by a reduced density. Their unique properties can be controlled by modifying size and chemical composition of the granular and interfacial regions. Ni50Ti45Cu5 amorphous films were obtained by magnetron sputtering and analyzed to determine their nanoscale morphology and the formation mechanisms. The nanoglasses were noted to have a hierarchical nano-columnar structure with the smallest Ni-rich (Ni:Ti ratio of ca. 5:3) amorphous columns with diameters of about 8nm and Ti-rich glassy interfacial regions with a substantially lower density. The results were obtained utilizing X-ray diffraction and different microscopic methods, e.g., atomic force microscopy and transmission electron microscopy. A detailed analysis indicates the complexity of the formation mechanisms of topologically and chemically distinguishable structural units with curvature driven surface diffusion, surface mobility, self-shadowing and internal stresses as the most important parameters. Common and simple synthesis method and the possibility for easy modification of the morphology and, consequently, the physical properties offer an opportunity for intensive studies of this new class of materials, opening the way towards possible applications. •Ni50Ti45Cu5 thin film nanoglasses were synthesized by magnetron sputtering.•Ti amorphous interfacial phase with reduced density is observed.•Stabilization of interfaces by specific local thermodynamic conditions.