Two Compounds Constructed from Bimolybdenum-Capped Sandwich-Type Tetra-Ni-molybdogermanate and N‑Donor Multidentate Ligand

Two organic–inorganic hybrid bimolybdenum-capped tetra-NiII sandwich-type molybdogermanates, namely, (H2L)4[Ni4(H2O)2­{B-α-GeMo9O34 (MoO2)}2]·6H2O (1), [Ni2(HL)4(H2O)2]­[Ni4(H2O)2­{B-α-GeMo9O34(MoO2)}2]·12H2O (2), L = 2,4,5-tri­(4-pyridyl)­imidazole, were prepared with hydrothermal synthesis method...

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Published in:Inorganic chemistry 2015-08, Vol.54 (15), p.7165-7170
Main Authors: Zhou, Shi, Liu, Bo, Shi, Tian, Li, Xiao-Min, Chen, Ya-Guang
Format: Article
Language:English
Subjects:
Construction
Covalence
Diffraction
Hydrogen bonds
Infrared spectroscopy
Ligands
Magnetic properties
X-rays
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Liu, Bo
Shi, Tian
Li, Xiao-Min
Chen, Ya-Guang
description Two organic–inorganic hybrid bimolybdenum-capped tetra-NiII sandwich-type molybdogermanates, namely, (H2L)4[Ni4(H2O)2­{B-α-GeMo9O34 (MoO2)}2]·6H2O (1), [Ni2(HL)4(H2O)2]­[Ni4(H2O)2­{B-α-GeMo9O34(MoO2)}2]·12H2O (2), L = 2,4,5-tri­(4-pyridyl)­imidazole, were prepared with hydrothermal synthesis method and characterized by elemental analysis, IR spectroscopy, powder X-ray diffraction, thermogravimetric analysis, and single-crystal X-ray diffraction. Their magnetic properties and electrochemical properties were investigated. The results show that compounds 1 and 2 contain a new bimolybdenum-capped sandwich-type heteropolymolybdate anion, [Ni4(H2O)2­{B-α-GeMo9O34(MoO2)}2]8–. The compound 1 is a zero-dimensional supramolecular compound, and the supramolecular architecture of compound 2 is constructed from covalent layers through hydrogen bonds and π–π interaction. The two compounds both present electrocatalytic activities for the reduction of nitrite.
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Chem</addtitle><date>2015-08-03</date><risdate>2015</risdate><volume>54</volume><issue>15</issue><spage>7165</spage><epage>7170</epage><pages>7165-7170</pages><issn>0020-1669</issn><eissn>1520-510X</eissn><abstract>Two organic–inorganic hybrid bimolybdenum-capped tetra-NiII sandwich-type molybdogermanates, namely, (H2L)4[Ni4(H2O)2­{B-α-GeMo9O34 (MoO2)}2]·6H2O (1), [Ni2(HL)4(H2O)2]­[Ni4(H2O)2­{B-α-GeMo9O34(MoO2)}2]·12H2O (2), L = 2,4,5-tri­(4-pyridyl)­imidazole, were prepared with hydrothermal synthesis method and characterized by elemental analysis, IR spectroscopy, powder X-ray diffraction, thermogravimetric analysis, and single-crystal X-ray diffraction. Their magnetic properties and electrochemical properties were investigated. The results show that compounds 1 and 2 contain a new bimolybdenum-capped sandwich-type heteropolymolybdate anion, [Ni4(H2O)2­{B-α-GeMo9O34(MoO2)}2]8–. The compound 1 is a zero-dimensional supramolecular compound, and the supramolecular architecture of compound 2 is constructed from covalent layers through hydrogen bonds and π–π interaction. The two compounds both present electrocatalytic activities for the reduction of nitrite.</abstract><cop>United States</cop><pub>American Chemical Society</pub><pmid>26200432</pmid><doi>10.1021/acs.inorgchem.5b00227</doi><tpages>6</tpages></addata></record>
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source American Chemical Society:Jisc Collections:American Chemical Society Read & Publish Agreement 2022-2024 (Reading list)
subjects Construction
Covalence
Diffraction
Hydrogen bonds
Infrared spectroscopy
Ligands
Magnetic properties
X-rays
title Two Compounds Constructed from Bimolybdenum-Capped Sandwich-Type Tetra-Ni-molybdogermanate and N‑Donor Multidentate Ligand
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