C–O/C–H Coupling of Polyfluoroarenes with Aryl Carbamates by Cooperative Ni/Cu Catalysis

Cross-coupling of polyfluoroarenes with aryl carbamates through the cleavage of both sp2 C–O and C–H bonds is reported. The reaction conditions are simple, and only transition-metal catalysts and ligands are essential. Mechanistic studies indicated that Ni catalyst played an important role in activa...

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Published in:Organic letters 2016-06, Vol.18 (11), p.2548-2551
Main Authors: Wang, Yang, Wu, Song-Bai, Shi, Wen-Juan, Shi, Zhang-Jie
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Language:English
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creator Wang, Yang
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Shi, Wen-Juan
Shi, Zhang-Jie
description Cross-coupling of polyfluoroarenes with aryl carbamates through the cleavage of both sp2 C–O and C–H bonds is reported. The reaction conditions are simple, and only transition-metal catalysts and ligands are essential. Mechanistic studies indicated that Ni catalyst played an important role in activating C–O bond, while the Cu one in activating C–H Bond. The developed system proved to be effective for cross-coupling of terminal alkynes with aryl carbamates.
doi_str_mv 10.1021/acs.orglett.6b00819
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title C–O/C–H Coupling of Polyfluoroarenes with Aryl Carbamates by Cooperative Ni/Cu Catalysis
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