Validated UPLC-MS/MS Methods To Quantitate Free and Conjugated Alternaria Toxins in Commercially Available Tomato Products and Fruit and Vegetable Juices in Belgium

Ultraperformance liquid chromatography tandem mass spectrometry and Quick, Easy, Cheap, Effective, Rugged, and Safe based analytical methodologies to quantitate both free (alternariol (1), alternariol monomethyl ether (2), tenuazonic acid (3), tentoxin (4), altenuene (5), altertoxin-I (6)) and conju...

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Published in:Journal of agricultural and food chemistry 2016-06, Vol.64 (24), p.5101-5109
Main Authors: Walravens, Jeroen, Mikula, Hannes, Rychlik, Michael, Asam, Stefan, Devos, Tom, Njumbe Ediage, Emmanuel, Diana Di Mavungu, José, Jacxsens, Liesbeth, Van Landschoot, Anita, Vanhaecke, Lynn, De Saeger, Sarah
Format: Article
Language:English
Subjects:
Alternaria - chemistry
Alternaria - metabolism
Belgium
Chromatography, High Pressure Liquid - methods
Food Contamination - analysis
Food Contamination - economics
Fruit and Vegetable Juices - analysis
Fruit and Vegetable Juices - economics
Fruit and Vegetable Juices - microbiology
Mycotoxins - chemistry
Tandem Mass Spectrometry - methods
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creator Walravens, Jeroen
Mikula, Hannes
Rychlik, Michael
Asam, Stefan
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Jacxsens, Liesbeth
Van Landschoot, Anita
Vanhaecke, Lynn
De Saeger, Sarah
description Ultraperformance liquid chromatography tandem mass spectrometry and Quick, Easy, Cheap, Effective, Rugged, and Safe based analytical methodologies to quantitate both free (alternariol (1), alternariol monomethyl ether (2), tenuazonic acid (3), tentoxin (4), altenuene (5), altertoxin-I (6)) and conjugated (sulfates and glucosides of 1 and 2) Alternaria toxins in fruit and vegetable juices and tomato products were developed and validated. Acceptable limits of quantitation (0.7–5.7 μg/kg), repeatability (RSDr < 15.7%), reproducibility (RSDR < 17.9%), and apparent recovery (87.0–110.6%) were obtained for all analytes in all matrices investigated. 129 commercial foodstuffs were analyzed, and 3 was detected in 100% of tomato product samples (
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ispartof Journal of agricultural and food chemistry, 2016-06, Vol.64 (24), p.5101-5109
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source American Chemical Society:Jisc Collections:American Chemical Society Read & Publish Agreement 2022-2024 (Reading list)
subjects Alternaria - chemistry
Alternaria - metabolism
Belgium
Chromatography, High Pressure Liquid - methods
Food Contamination - analysis
Food Contamination - economics
Fruit and Vegetable Juices - analysis
Fruit and Vegetable Juices - economics
Fruit and Vegetable Juices - microbiology
Mycotoxins - chemistry
Tandem Mass Spectrometry - methods
title Validated UPLC-MS/MS Methods To Quantitate Free and Conjugated Alternaria Toxins in Commercially Available Tomato Products and Fruit and Vegetable Juices in Belgium
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