Catalytic dehydrocoupling of amine-boranes and amines into diaminoboranes: isolation of a Pt(), Shimoi-type, η-BH complex

The platinum complex [Pt(I t Bu′)(I t Bu)][BAr F ] is a very efficient catalyst in the synthesis of diaminoboranes through dehydrocoupling of amine-boranes and amines. Shimoi-type, η 1 -BH complexes are key intermediates in the process. The platinum complex [Pt(I t Bu′)(I t Bu)][BAr F ] is a very ef...

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Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2016-06, Vol.52 (54), p.8389-8392
Main Authors: Roselló-Merino, Marta, Rama, Raquel J, Díez, Josefina, Conejero, Salvador
Format: Article
Language:English
Online Access:Get full text
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Summary:The platinum complex [Pt(I t Bu′)(I t Bu)][BAr F ] is a very efficient catalyst in the synthesis of diaminoboranes through dehydrocoupling of amine-boranes and amines. Shimoi-type, η 1 -BH complexes are key intermediates in the process. The platinum complex [Pt(I t Bu′)(I t Bu)][BAr F ] is a very efficient catalyst in the synthesis of diaminoboranes through dehydrocoupling of amine-boranes and amines.
ISSN:1359-7345
1364-548X
DOI:10.1039/c6cc02720b