Acylation of cellulose in reversible ionic liquids

1,8-Diazabicyclo[5.4.0]undec-7-ene (DBU), in conjunction with methanol after CO sub(2) capture in DMSO created a new solvent capable of dissolving up to 8 wt% of cellulose, which could be applied as a highly efficient reaction media for the synthesis of cellulose esters under mild conditions.

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Bibliographic Details
Published in:Green chemistry : an international journal and green chemistry resource : GC 2014-01, Vol.16 (6), p.3018-3023
Main Authors: Yang, Yunlong, Xie, Haibo, Liu, Enhui
Format: Article
Language:English
Subjects:
Carbon capture and storage
Carbon dioxide
Cellulose
Cellulose esters
Ionic liquids
Methyl alcohol
Solvents
Synthesis (chemistry)
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Description
Summary:1,8-Diazabicyclo[5.4.0]undec-7-ene (DBU), in conjunction with methanol after CO sub(2) capture in DMSO created a new solvent capable of dissolving up to 8 wt% of cellulose, which could be applied as a highly efficient reaction media for the synthesis of cellulose esters under mild conditions.
ISSN:1463-9262
1463-9270
DOI:10.1039/c4gc00199k