Synthesis and physicochemical properties of new zirconium fluoro complexes (NH sub(4)) sub(4.5)M sub(4.5)Zr sub(6)F sub(33 ) . 3H sub(2)O (M = Li, K, Rb, Cs)

Ammonium-containing zirconium fluoro complexes crystallizing in monoclinic system were synthesized and studied. Their unit cell parameters were determined. The IR absorption spectra of the synthesized fluoro complexes were studied in the region of 350-4000 cm super(-1).

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Bibliographic Details
Published in:Russian journal of inorganic chemistry 2014-12, Vol.59 (12), p.1396-1402
Main Authors: Antokhina, T F, Kaidalova, T A, Gerasimenko, A V, Pushilin, MA, Savchenko, N N, Ignat'eva, L N
Format: Article
Language:English
Subjects:
Absorption spectra
Crystallization
Infrared spectroscopy
Lithium
Synthesis
Unit cell
Zirconium
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Description
Summary:Ammonium-containing zirconium fluoro complexes crystallizing in monoclinic system were synthesized and studied. Their unit cell parameters were determined. The IR absorption spectra of the synthesized fluoro complexes were studied in the region of 350-4000 cm super(-1).
ISSN:0036-0236
1531-8613
DOI:10.1134/S003602361412002X