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Synthesis and physicochemical properties of new zirconium fluoro complexes (NH sub(4)) sub(4.5)M sub(4.5)Zr sub(6)F sub(33 ) . 3H sub(2)O (M = Li, K, Rb, Cs)

Ammonium-containing zirconium fluoro complexes crystallizing in monoclinic system were synthesized and studied. Their unit cell parameters were determined. The IR absorption spectra of the synthesized fluoro complexes were studied in the region of 350-4000 cm super(-1).

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Published in:Russian journal of inorganic chemistry 2014-12, Vol.59 (12), p.1396-1402
Main Authors: Antokhina, T F, Kaidalova, T A, Gerasimenko, A V, Pushilin, MA, Savchenko, N N, Ignat'eva, L N
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container_issue 12
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container_title Russian journal of inorganic chemistry
container_volume 59
creator Antokhina, T F
Kaidalova, T A
Gerasimenko, A V
Pushilin, MA
Savchenko, N N
Ignat'eva, L N
description Ammonium-containing zirconium fluoro complexes crystallizing in monoclinic system were synthesized and studied. Their unit cell parameters were determined. The IR absorption spectra of the synthesized fluoro complexes were studied in the region of 350-4000 cm super(-1).
doi_str_mv 10.1134/S003602361412002X
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source Springer Nature
subjects Absorption spectra
Crystallization
Infrared spectroscopy
Lithium
Synthesis
Unit cell
Zirconium
title Synthesis and physicochemical properties of new zirconium fluoro complexes (NH sub(4)) sub(4.5)M sub(4.5)Zr sub(6)F sub(33 ) . 3H sub(2)O (M = Li, K, Rb, Cs)
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