Porous polyoxadiazole membranes for harsh environment

• Published in: Journal of membrane science 2013-10, Vol.445, p.127-134
• Main Authors: Maab, Husnul, Pereira Nunes, Suzana
• Format: Article
• Language: English
• Subjects: Applied sciences; artificial membranes; Catalysts; ceramics; Chemistry; Colloidal state and disperse state; Cut-off; Exact sciences and technology; Exchange resins and membranes; Forms of application and semi-finished materials; General and physical chemistry; isopropyl alcohol; Membranes; molecular weight; Morphology; Organophilic ultrafiltration; oxidative stability; pharmaceutical industry; Phase shift; Polymer industry, paints, wood; Polyoxadiazole; Polystyrene resins; polystyrenes; Solvent resistant membrane; Solvents; Stability; sulfuric acid; Technology of polymers; temperature; thermal analysis
• ISSN: 0376-7388; 1873-3123
• DOI: 10.1016/j.memsci.2013.05.038

A series of polyoxadiazoles with exceptionally high stability at temperatures as high as 370°C and in oxidative medium has been synthesized by polycondensation and manufactured into porous membranes by phase inversion. The membranes were characterized by thermal analysis (TGA), chemical stability was measured by immersion test, oxidative stability by Fenton's test, pore diameter by porosimetry and the morphology by FESEM. The polymers are soluble only in sulfuric acid and are stable in organic solvents like NMP, THF and isopropanol. The membranes selectivity was confirmed by separation of polystyrene standards with different molecular weights. Most membranes were characterized as having a cut-off of 60,000g/mol. Being stable under harsh environments, the membranes have incomparable characteristics with perspectives of application in chemical and pharmaceutical industry, catalytic reactors, in combination with oxidative processes and other applications so far envisioned only for ceramic membranes. [Display omitted] •Polymeric membranes for operation in conditions dominated by ceramic membranes.•Polyoxadiazoles with alkyl, phenyl, diphenyl ether and diphenyl sulfone groups.•Porous polyoxadiazole membranes stable in temperature as high as 370°C•Porous polyoxadiazole membranes stable in highly oxidative medium (Fenton's test).•New membranes for solvent resistant ultrafiltration.