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New Polymeric Materials Based on Element-Blocks

The concept and representative examples of “element-block polymers” are described. A structural unit consisting of various groups of elements is called an “element-block.” In this review, unique properties of “element-block polymers” composed of organoboron complexes, o-carboranes, and polyhedral ol...

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Bibliographic Details
Published in:Bulletin of the Chemical Society of Japan 2015-05, Vol.88 (5), p.633-643
Main Authors: Chujo, Yoshiki, Tanaka, Kazuo
Format: Article
Language:English
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Summary:The concept and representative examples of “element-block polymers” are described. A structural unit consisting of various groups of elements is called an “element-block.” In this review, unique properties of “element-block polymers” composed of organoboron complexes, o-carboranes, and polyhedral oligomeric silsesquioxanes as typical examples of element blocks are illustrated. The design and synthesis of new element-blocks and development of methods forming higher-order structures for realizing the desired functions based on a bottom-up approach are explained.
ISSN:0009-2673
1348-0634
DOI:10.1246/bcsj.20150081