Hetero-bimetallic metal-organic polyhedra

Porous metal-organic polyhedra (MOPs), constructed from heterometallic Pd(II)-M(II) (M = Cu, Ni, Zn) paddlewheel nodes and 5-tert-butyl-1,3-benzenedicarboxylate organic links, were prepared in which the Pd(II) ions preferentially line the inner surface of the cage molecules. Careful activation produ...

Full description

Saved in:
Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2016-01, Vol.52 (2), p.276-279
Main Authors: Teo, Jesse M, Coghlan, Campbell J, Evans, Jack D, Tsivion, Ehud, Head-Gordon, Martin, Sumby, Christopher J, Doonan, Christian J
Format: Article
Language:English
Subjects:
Activation
Cage molecules
Nickel
Polyhedra
Polyhedrons
Surface chemistry
Three dimensional
Transition metals
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
cited_by cdi_FETCH-LOGICAL-c422t-a0ae0bb4c5b26b16773f4eada22605edd1f51c9db58906313ffdb33e4ec4a2103
cites cdi_FETCH-LOGICAL-c422t-a0ae0bb4c5b26b16773f4eada22605edd1f51c9db58906313ffdb33e4ec4a2103
container_end_page 279
container_issue 2
container_start_page 276
container_title Chemical communications (Cambridge, England)
container_volume 52
creator Teo, Jesse M
Coghlan, Campbell J
Evans, Jack D
Tsivion, Ehud
Head-Gordon, Martin
Sumby, Christopher J
Doonan, Christian J
description Porous metal-organic polyhedra (MOPs), constructed from heterometallic Pd(II)-M(II) (M = Cu, Ni, Zn) paddlewheel nodes and 5-tert-butyl-1,3-benzenedicarboxylate organic links, were prepared in which the Pd(II) ions preferentially line the inner surface of the cage molecules. Careful activation produces co-ordinatively unsaturated 3d transition metal sites on the external MOP surfaces giving rise to H2 adsorption enthalpies in excess of -12 kJ mol(-1).
doi_str_mv 10.1039/c5cc08336b
format article
fullrecord <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_1800466374</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>1750431732</sourcerecordid><originalsourceid>FETCH-LOGICAL-c422t-a0ae0bb4c5b26b16773f4eada22605edd1f51c9db58906313ffdb33e4ec4a2103</originalsourceid><addsrcrecordid>eNqFkE1Lw0AQhhdRbK1e_AHiUYXV3Z39SI42qBUKXhS8hf2YaCRp6m566L83_dCrc5ln4OGFeQk55-yWM8jvvPKeZQDaHZAxBy2pktn74YZVTg1INSInKX2xYbjKjslIaDUAM2NyPcMeY0dd3WJvm6b2l1ugXfywi-Fads36E0O0p-Sosk3Cs_2ekLfHh9diRucvT8_F_Zx6KURPLbPInJNeOaEd18ZAJdEGK4RmCkPgleI-D05lOdPAoaqCA0CJXlox_DMhV7vcZey-V5j6sq2Tx6axC-xWqeQZY1JrMPJ_1SgmgRsQg3qzU33sUopYlctYtzauS87KTYtloYpi2-J0kC_2uSvXYvhTf2uDH8H3a5Y</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>1750431732</pqid></control><display><type>article</type><title>Hetero-bimetallic metal-organic polyhedra</title><source>Royal Society of Chemistry:Jisc Collections:Royal Society of Chemistry Read and Publish 2022-2024 (reading list)</source><creator>Teo, Jesse M ; Coghlan, Campbell J ; Evans, Jack D ; Tsivion, Ehud ; Head-Gordon, Martin ; Sumby, Christopher J ; Doonan, Christian J</creator><creatorcontrib>Teo, Jesse M ; Coghlan, Campbell J ; Evans, Jack D ; Tsivion, Ehud ; Head-Gordon, Martin ; Sumby, Christopher J ; Doonan, Christian J</creatorcontrib><description>Porous metal-organic polyhedra (MOPs), constructed from heterometallic Pd(II)-M(II) (M = Cu, Ni, Zn) paddlewheel nodes and 5-tert-butyl-1,3-benzenedicarboxylate organic links, were prepared in which the Pd(II) ions preferentially line the inner surface of the cage molecules. Careful activation produces co-ordinatively unsaturated 3d transition metal sites on the external MOP surfaces giving rise to H2 adsorption enthalpies in excess of -12 kJ mol(-1).</description><identifier>ISSN: 1359-7345</identifier><identifier>EISSN: 1364-548X</identifier><identifier>DOI: 10.1039/c5cc08336b</identifier><identifier>PMID: 26515807</identifier><language>eng</language><publisher>England</publisher><subject>Activation ; Cage molecules ; Nickel ; Polyhedra ; Polyhedrons ; Surface chemistry ; Three dimensional ; Transition metals</subject><ispartof>Chemical communications (Cambridge, England), 2016-01, Vol.52 (2), p.276-279</ispartof><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c422t-a0ae0bb4c5b26b16773f4eada22605edd1f51c9db58906313ffdb33e4ec4a2103</citedby><cites>FETCH-LOGICAL-c422t-a0ae0bb4c5b26b16773f4eada22605edd1f51c9db58906313ffdb33e4ec4a2103</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27901,27902</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/26515807$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Teo, Jesse M</creatorcontrib><creatorcontrib>Coghlan, Campbell J</creatorcontrib><creatorcontrib>Evans, Jack D</creatorcontrib><creatorcontrib>Tsivion, Ehud</creatorcontrib><creatorcontrib>Head-Gordon, Martin</creatorcontrib><creatorcontrib>Sumby, Christopher J</creatorcontrib><creatorcontrib>Doonan, Christian J</creatorcontrib><title>Hetero-bimetallic metal-organic polyhedra</title><title>Chemical communications (Cambridge, England)</title><addtitle>Chem Commun (Camb)</addtitle><description>Porous metal-organic polyhedra (MOPs), constructed from heterometallic Pd(II)-M(II) (M = Cu, Ni, Zn) paddlewheel nodes and 5-tert-butyl-1,3-benzenedicarboxylate organic links, were prepared in which the Pd(II) ions preferentially line the inner surface of the cage molecules. Careful activation produces co-ordinatively unsaturated 3d transition metal sites on the external MOP surfaces giving rise to H2 adsorption enthalpies in excess of -12 kJ mol(-1).</description><subject>Activation</subject><subject>Cage molecules</subject><subject>Nickel</subject><subject>Polyhedra</subject><subject>Polyhedrons</subject><subject>Surface chemistry</subject><subject>Three dimensional</subject><subject>Transition metals</subject><issn>1359-7345</issn><issn>1364-548X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2016</creationdate><recordtype>article</recordtype><recordid>eNqFkE1Lw0AQhhdRbK1e_AHiUYXV3Z39SI42qBUKXhS8hf2YaCRp6m566L83_dCrc5ln4OGFeQk55-yWM8jvvPKeZQDaHZAxBy2pktn74YZVTg1INSInKX2xYbjKjslIaDUAM2NyPcMeY0dd3WJvm6b2l1ugXfywi-Fads36E0O0p-Sosk3Cs_2ekLfHh9diRucvT8_F_Zx6KURPLbPInJNeOaEd18ZAJdEGK4RmCkPgleI-D05lOdPAoaqCA0CJXlox_DMhV7vcZey-V5j6sq2Tx6axC-xWqeQZY1JrMPJ_1SgmgRsQg3qzU33sUopYlctYtzauS87KTYtloYpi2-J0kC_2uSvXYvhTf2uDH8H3a5Y</recordid><startdate>20160107</startdate><enddate>20160107</enddate><creator>Teo, Jesse M</creator><creator>Coghlan, Campbell J</creator><creator>Evans, Jack D</creator><creator>Tsivion, Ehud</creator><creator>Head-Gordon, Martin</creator><creator>Sumby, Christopher J</creator><creator>Doonan, Christian J</creator><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope></search><sort><creationdate>20160107</creationdate><title>Hetero-bimetallic metal-organic polyhedra</title><author>Teo, Jesse M ; Coghlan, Campbell J ; Evans, Jack D ; Tsivion, Ehud ; Head-Gordon, Martin ; Sumby, Christopher J ; Doonan, Christian J</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c422t-a0ae0bb4c5b26b16773f4eada22605edd1f51c9db58906313ffdb33e4ec4a2103</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2016</creationdate><topic>Activation</topic><topic>Cage molecules</topic><topic>Nickel</topic><topic>Polyhedra</topic><topic>Polyhedrons</topic><topic>Surface chemistry</topic><topic>Three dimensional</topic><topic>Transition metals</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Teo, Jesse M</creatorcontrib><creatorcontrib>Coghlan, Campbell J</creatorcontrib><creatorcontrib>Evans, Jack D</creatorcontrib><creatorcontrib>Tsivion, Ehud</creatorcontrib><creatorcontrib>Head-Gordon, Martin</creatorcontrib><creatorcontrib>Sumby, Christopher J</creatorcontrib><creatorcontrib>Doonan, Christian J</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Chemical communications (Cambridge, England)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Teo, Jesse M</au><au>Coghlan, Campbell J</au><au>Evans, Jack D</au><au>Tsivion, Ehud</au><au>Head-Gordon, Martin</au><au>Sumby, Christopher J</au><au>Doonan, Christian J</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Hetero-bimetallic metal-organic polyhedra</atitle><jtitle>Chemical communications (Cambridge, England)</jtitle><addtitle>Chem Commun (Camb)</addtitle><date>2016-01-07</date><risdate>2016</risdate><volume>52</volume><issue>2</issue><spage>276</spage><epage>279</epage><pages>276-279</pages><issn>1359-7345</issn><eissn>1364-548X</eissn><abstract>Porous metal-organic polyhedra (MOPs), constructed from heterometallic Pd(II)-M(II) (M = Cu, Ni, Zn) paddlewheel nodes and 5-tert-butyl-1,3-benzenedicarboxylate organic links, were prepared in which the Pd(II) ions preferentially line the inner surface of the cage molecules. Careful activation produces co-ordinatively unsaturated 3d transition metal sites on the external MOP surfaces giving rise to H2 adsorption enthalpies in excess of -12 kJ mol(-1).</abstract><cop>England</cop><pmid>26515807</pmid><doi>10.1039/c5cc08336b</doi><tpages>4</tpages><oa>free_for_read</oa></addata></record>
fulltext fulltext
identifier ISSN: 1359-7345
ispartof Chemical communications (Cambridge, England), 2016-01, Vol.52 (2), p.276-279
issn 1359-7345
1364-548X
language eng
recordid cdi_proquest_miscellaneous_1800466374
source Royal Society of Chemistry:Jisc Collections:Royal Society of Chemistry Read and Publish 2022-2024 (reading list)
subjects Activation
Cage molecules
Nickel
Polyhedra
Polyhedrons
Surface chemistry
Three dimensional
Transition metals
title Hetero-bimetallic metal-organic polyhedra
url http://sfxeu10.hosted.exlibrisgroup.com/loughborough?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-02-04T06%3A58%3A12IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Hetero-bimetallic%20metal-organic%20polyhedra&rft.jtitle=Chemical%20communications%20(Cambridge,%20England)&rft.au=Teo,%20Jesse%20M&rft.date=2016-01-07&rft.volume=52&rft.issue=2&rft.spage=276&rft.epage=279&rft.pages=276-279&rft.issn=1359-7345&rft.eissn=1364-548X&rft_id=info:doi/10.1039/c5cc08336b&rft_dat=%3Cproquest_cross%3E1750431732%3C/proquest_cross%3E%3Cgrp_id%3Ecdi_FETCH-LOGICAL-c422t-a0ae0bb4c5b26b16773f4eada22605edd1f51c9db58906313ffdb33e4ec4a2103%3C/grp_id%3E%3Coa%3E%3C/oa%3E%3Curl%3E%3C/url%3E&rft_id=info:oai/&rft_pqid=1750431732&rft_id=info:pmid/26515807&rfr_iscdi=true