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Bismuth oxychloride hollow microspheres with high visible light photocatalytic activity
Hollow microspheres of two bismuth oxychlorides, BiOC1 and Bi24031Cl10, were successfully synthesized using carbonaceous microsphere sacrificial templates. The phase evolution from BiOC1 to Bi24031Cl10 was easily realized by heating the former at 600 ℃. With a uniform diameter of about 200 nm, an av...
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| Published in: | Nano research 2016-03, Vol.9 (3), p.593-601 |
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| creator | Cui, Pengzhen Wang, Jiali Wang, Zumin Chen, Jun Xing, Xianran Wang, Lianzhou Yu, Ranbo |
| description | Hollow microspheres of two bismuth oxychlorides, BiOC1 and Bi24031Cl10, were successfully synthesized using carbonaceous microsphere sacrificial templates. The phase evolution from BiOC1 to Bi24031Cl10 was easily realized by heating the former at 600 ℃. With a uniform diameter of about 200 nm, an average shell thickness of 40 nm, and basic nanosheets of 〈20 nm, the hollow microspheres of both BLOC1 and Bi24031Cl10 showed high visible light photocatalytic activity towards the degradation of Rhodamine B （RhB）. Besides the effective photo- sensitization process and efficient photointroduced carrier separation, the high photocatalytic activity was believed to result from their hollow-structure- dependent large visible light absorption. Moreover, as a chlorine-deficient analogue, the Bi24031Cl10 hollow spheres possessed a narrower band gap, more dispersive band structure, and higher photocarrier conversion efficiency, which further helped them to exhibit better photocatalytic activity. |
| doi_str_mv | 10.1007/s12274-015-0939-z |
| format | article |
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The phase evolution from BiOC1 to Bi24031Cl10 was easily realized by heating the former at 600 ℃. With a uniform diameter of about 200 nm, an average shell thickness of 40 nm, and basic nanosheets of 〈20 nm, the hollow microspheres of both BLOC1 and Bi24031Cl10 showed high visible light photocatalytic activity towards the degradation of Rhodamine B （RhB）. Besides the effective photo- sensitization process and efficient photointroduced carrier separation, the high photocatalytic activity was believed to result from their hollow-structure- dependent large visible light absorption. Moreover, as a chlorine-deficient analogue, the Bi24031Cl10 hollow spheres possessed a narrower band gap, more dispersive band structure, and higher photocarrier conversion efficiency, which further helped them to exhibit better photocatalytic activity.</description><identifier>ISSN: 1998-0124</identifier><identifier>EISSN: 1998-0000</identifier><identifier>DOI: 10.1007/s12274-015-0939-z</identifier><language>eng</language><publisher>Beijing: Tsinghua University Press</publisher><subject>Atomic/Molecular Structure and Spectra ; Band structure of solids ; Banded structure ; Biomedicine ; Biotechnology ; Bismuth ; Catalytic activity ; Chemistry and Materials Science ; Chlorine ; Condensed Matter Physics ; Conversion ; Electromagnetic absorption ; Evolution ; Materials Science ; Microspheres ; Nanostructure ; Nanotechnology ; Photocatalysis ; Photodegradation ; Photosensitization ; Research Article ; Rhodamine ; 光催化活性 ; 光转换效率 ; 可见光吸收 ; 氯氧化铋 ; 空心微球 ; 空心结构 ; 能带结构</subject><ispartof>Nano research, 2016-03, Vol.9 (3), p.593-601</ispartof><rights>Tsinghua University Press and Springer-Verlag Berlin Heidelberg 2016</rights><rights>Nano Research is a copyright of Springer, (2016). All Rights Reserved.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c376t-a5e0aa136461e4930675e2f7a24bdfe85a1e4e80fe901e515ed1e9ca7c06f03a3</citedby><cites>FETCH-LOGICAL-c376t-a5e0aa136461e4930675e2f7a24bdfe85a1e4e80fe901e515ed1e9ca7c06f03a3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Uhttp://image.cqvip.com/vip1000/qk/71233X/71233X.jpg</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Cui, Pengzhen</creatorcontrib><creatorcontrib>Wang, Jiali</creatorcontrib><creatorcontrib>Wang, Zumin</creatorcontrib><creatorcontrib>Chen, Jun</creatorcontrib><creatorcontrib>Xing, Xianran</creatorcontrib><creatorcontrib>Wang, Lianzhou</creatorcontrib><creatorcontrib>Yu, Ranbo</creatorcontrib><title>Bismuth oxychloride hollow microspheres with high visible light photocatalytic activity</title><title>Nano research</title><addtitle>Nano Res</addtitle><addtitle>Nano Research</addtitle><description>Hollow microspheres of two bismuth oxychlorides, BiOC1 and Bi24031Cl10, were successfully synthesized using carbonaceous microsphere sacrificial templates. The phase evolution from BiOC1 to Bi24031Cl10 was easily realized by heating the former at 600 ℃. With a uniform diameter of about 200 nm, an average shell thickness of 40 nm, and basic nanosheets of 〈20 nm, the hollow microspheres of both BLOC1 and Bi24031Cl10 showed high visible light photocatalytic activity towards the degradation of Rhodamine B （RhB）. Besides the effective photo- sensitization process and efficient photointroduced carrier separation, the high photocatalytic activity was believed to result from their hollow-structure- dependent large visible light absorption. Moreover, as a chlorine-deficient analogue, the Bi24031Cl10 hollow spheres possessed a narrower band gap, more dispersive band structure, and higher photocarrier conversion efficiency, which further helped them to exhibit better photocatalytic activity.</description><subject>Atomic/Molecular Structure and Spectra</subject><subject>Band structure of solids</subject><subject>Banded structure</subject><subject>Biomedicine</subject><subject>Biotechnology</subject><subject>Bismuth</subject><subject>Catalytic activity</subject><subject>Chemistry and Materials Science</subject><subject>Chlorine</subject><subject>Condensed Matter Physics</subject><subject>Conversion</subject><subject>Electromagnetic absorption</subject><subject>Evolution</subject><subject>Materials 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Article</subject><subject>Rhodamine</subject><subject>光催化活性</subject><subject>光转换效率</subject><subject>可见光吸收</subject><subject>氯氧化铋</subject><subject>空心微球</subject><subject>空心结构</subject><subject>能带结构</subject><issn>1998-0124</issn><issn>1998-0000</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2016</creationdate><recordtype>article</recordtype><recordid>eNp9kE9PGzEQxVcVSFDgA3BbtZdels7YXu_62CL-VIrUSxFHyzizWSMnDraTNPn0OAptpR7wxR7r997MvKq6RLhCgO5rQsY60QC2DSiumt2H6hSV6hso5-jPG5k4qT6m9AwgGYr-tHr87tJ8lcc6_N7a0YfoplSPwfuwqefOxpCWI0VK9cYVaHSzsV675J481b4UuV6OIQdrsvHb7GxtbHZrl7fn1fFgfKKLt_useri9-XV930x-3v24_jZpLO9kbkxLYAxyKSSSUBxk1xIbOsPE03SgvjXlm3oYSAFSiy1NkZQ1nQU5ADf8rPpy8F3G8LKilPXcJUvemwWFVdLYAwjVcgUF_fwf-hxWcVGm0wwARSd5LwqFB2q_e4o06GV0cxO3GkHvo9aHqHWJWu-j1ruiYQdNKuxiRvGf83uiT2-NxrCYvRTd305S9gz6ViB_BRNFjpU</recordid><startdate>20160301</startdate><enddate>20160301</enddate><creator>Cui, Pengzhen</creator><creator>Wang, Jiali</creator><creator>Wang, 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Ranbo</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Bismuth oxychloride hollow microspheres with high visible light photocatalytic activity</atitle><jtitle>Nano research</jtitle><stitle>Nano Res</stitle><addtitle>Nano Research</addtitle><date>2016-03-01</date><risdate>2016</risdate><volume>9</volume><issue>3</issue><spage>593</spage><epage>601</epage><pages>593-601</pages><issn>1998-0124</issn><eissn>1998-0000</eissn><abstract>Hollow microspheres of two bismuth oxychlorides, BiOC1 and Bi24031Cl10, were successfully synthesized using carbonaceous microsphere sacrificial templates. The phase evolution from BiOC1 to Bi24031Cl10 was easily realized by heating the former at 600 ℃. With a uniform diameter of about 200 nm, an average shell thickness of 40 nm, and basic nanosheets of 〈20 nm, the hollow microspheres of both BLOC1 and Bi24031Cl10 showed high visible light photocatalytic activity towards the degradation of Rhodamine B （RhB）. Besides the effective photo- sensitization process and efficient photointroduced carrier separation, the high photocatalytic activity was believed to result from their hollow-structure- dependent large visible light absorption. Moreover, as a chlorine-deficient analogue, the Bi24031Cl10 hollow spheres possessed a narrower band gap, more dispersive band structure, and higher photocarrier conversion efficiency, which further helped them to exhibit better photocatalytic activity.</abstract><cop>Beijing</cop><pub>Tsinghua University Press</pub><doi>10.1007/s12274-015-0939-z</doi><tpages>9</tpages></addata></record> |
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| identifier | ISSN: 1998-0124 |
| ispartof | Nano research, 2016-03, Vol.9 (3), p.593-601 |
| issn | 1998-0124 1998-0000 |
| language | eng |
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| source | Springer Nature |
| subjects | Atomic/Molecular Structure and Spectra Band structure of solids Banded structure Biomedicine Biotechnology Bismuth Catalytic activity Chemistry and Materials Science Chlorine Condensed Matter Physics Conversion Electromagnetic absorption Evolution Materials Science Microspheres Nanostructure Nanotechnology Photocatalysis Photodegradation Photosensitization Research Article Rhodamine 光催化活性 光转换效率 可见光吸收 氯氧化铋 空心微球 空心结构 能带结构 |
| title | Bismuth oxychloride hollow microspheres with high visible light photocatalytic activity |
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