Supercritical water oxidation of nitrogen compounds with multi-injection of oxygen

• Published in: The Journal of supercritical fluids 2013-08, Vol.80, p.23-29
• Main Authors: García-Jarana, M.B., Kings, I., Sánchez-Oneto, J., Portela, Juan R., Al-Duri, B.
• Format: Article
• Language: English
• Subjects: Continuous flow; Inlets; Multi-injection oxidant; N,N-Dimethylformamide; Nitrogen compounds; Oxidants; Oxidizing agents; Reactors; Supercritical fluids; Supercritical water oxidation
• ISSN: 0896-8446; 1872-8162
• DOI: 10.1016/j.supflu.2013.04.004

•A SCWO system with multi-injection of oxidant has been tested at laboratory scale.•DMF was studied as a representative organic compound that is difficult to oxidize.•Multi-oxidant experiments showed better results than single entry experiments.•The best position to supply the second injection seems to be at 3s in the experiments with a total residence time of 6s.•The optimum split-ratio was 75% of oxidant at the reactor inlet and 25% at the second injection. A supercritical water oxidation (SCWO) process with oxidant multi-injection was studied in a continuous flow system in which the same amount of oxidant feed is split between two points – a first injection at the reactor inlet and a second injection at one of the three different positions along the reactor. Under the same operating conditions, this multi-injection configuration showed advantages over the system with a single oxidant entry. Moreover, oxidant dosage in a SCWO reactor is a key aspect in energy management. In this work, experiments were performed to find the best oxidant dosage to obtain the maximum organic conversion. Experiments were carried out using N,N-dimethylformamide (DMF) as a model compound for nitrogen-containing hydrocarbons in wastewaters. All experiments were carried out at 250bar with an oxygen coefficient n=1 and a temperature of 400°C. Each experiment was carried out at five different residence times (2, 4, 6, 8 and 10s). Once the best configuration had been determined, the effect of temperature (400–550°C), initial organic concentration (5–30mM), oxygen coefficient (0.5–3) and residence time (2–10s) was investigated in the SCWO process of DMF.