Hyperbranched Polymers by Type II Photoinitiated Self-Condensing Vinyl Polymerization

Type II photoinitiated self‐condensing vinyl polymerization for the preparation of hyperbranched polymers is explored using 2‐hydroxyethyl methacrylate (HEMA) or 2‐(dimethylamino)ethyl methacrylate (DMAEMA), and methyl methacrylate as hydrogen donating inimers and comonomer, respectively, in the pre...

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Published in:Macromolecular rapid communications. 2016-04, Vol.37 (7), p.650-654
Main Authors: Aydogan, Cansu, Ciftci, Mustafa, Yagci, Yusuf
Format: Article
Language:English
Subjects:
Crosslinking
Density
Excitation
Hydrogen
hyperbranched polymers
Light
Magnetic Resonance Spectroscopy
Methacrylates - chemistry
Methylmethacrylate - chemistry
Photoinitiators
photopolymerization
Polymerization
Polymers
Polymers - chemistry
Polymethyl methacrylates
Polyvinyl Chloride - chemistry
Radicals
Spectroscopy, Fourier Transform Infrared
vinyl polymerization
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cited_by cdi_FETCH-LOGICAL-c5501-1bdaa73b07e126cae9269e9ec2b9b7189daad459fe3bd9480de6cb9de9a855c43
cites cdi_FETCH-LOGICAL-c5501-1bdaa73b07e126cae9269e9ec2b9b7189daad459fe3bd9480de6cb9de9a855c43
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creator Aydogan, Cansu
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Yagci, Yusuf
description Type II photoinitiated self‐condensing vinyl polymerization for the preparation of hyperbranched polymers is explored using 2‐hydroxyethyl methacrylate (HEMA) or 2‐(dimethylamino)ethyl methacrylate (DMAEMA), and methyl methacrylate as hydrogen donating inimers and comonomer, respectively, in the presence of benzophenone and camphorquinone under UV and visible light. Upon irradiation at the corresponding wavelength, the excited photoinitiator s hydrogen from HEMA or DMAEMA leading to the formation of initiating radicals. Depending on the concentration of inimers, type of the photoinitiator, and irradiation time, hyperbranched polymers with different branching densities and cross‐linked polymers are formed. Hyperbranched polymers with different branching density and cross‐linked polymers have been synthesized via self‐condensing Type II photoinitiated copolymerization of methyl methacrylate and 2‐hydroxyethyl methacrylate (HEMA) or 2‐(dimethylamino)ethyl methacrylate (DMAEMA) in the presence of benzophenone and camphorquinone. The method is based on the hydrogen ion from HEMA or DMAEMA by excited photoinitiator to form initiating radicals.
doi_str_mv 10.1002/marc.201500721
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source Wiley-Blackwell Read & Publish Collection
subjects Crosslinking
Density
Excitation
Hydrogen
hyperbranched polymers
Light
Magnetic Resonance Spectroscopy
Methacrylates - chemistry
Methylmethacrylate - chemistry
Photoinitiators
photopolymerization
Polymerization
Polymers
Polymers - chemistry
Polymethyl methacrylates
Polyvinyl Chloride - chemistry
Radicals
Spectroscopy, Fourier Transform Infrared
vinyl polymerization
title Hyperbranched Polymers by Type II Photoinitiated Self-Condensing Vinyl Polymerization
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