A New Mo(VI) Complex of (E)-2-(((5-hydroxypentyl)imino)methyl)-6-methoxyphenol: Synthesis, Characterization, and X-Ray Crystal Structure

A tridentate ONO Schiff base ligand, (E)-2-(((5-hydroxypentyl)imino)methyl)-6-methoxyphenol [H 2 L], and its Mo(VI) complex [MoL], have been synthesized and structurally characterized by elemental analysis, FT-IR, NMR, and UV-Vis spectroscopy. The structure of the Mo(VI) complex has been determined...

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Bibliographic Details
Published in:Synthesis and reactivity in inorganic, metal-organic, and nano-metal chemistry metal-organic, and nano-metal chemistry, 2016-06, Vol.46 (6), p.917-921
Main Authors: Sheikhshoaie, Iran, Ebrahimipour, S. Yousef, Shamsi, Somayeh
Format: Article
Language:English
Subjects:
Crystal structure
Crystals
Diffraction
Fourier transforms
Infrared spectroscopy
Ligands
Mo(VI) complex
ONO donor
Schiff base ligand
Schiff bases
spectroscopic characterization
X-rays
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Summary:A tridentate ONO Schiff base ligand, (E)-2-(((5-hydroxypentyl)imino)methyl)-6-methoxyphenol [H 2 L], and its Mo(VI) complex [MoL], have been synthesized and structurally characterized by elemental analysis, FT-IR, NMR, and UV-Vis spectroscopy. The structure of the Mo(VI) complex has been determined by single-crystal X-ray diffraction. This complex has octahedral geometry around central atom. Yellow crystals crystallize in orthorhombic, space group Pbca with a = 17.8718(10) Å, b = 17.4516(10) Å, c, 18.1872(10) Å and α = β = γ = 90°.
ISSN:1553-3174
1553-3182
DOI:10.1080/15533174.2014.989612