Modeling of a fluidized-bed photocatalytic reactor for water pollution abatement

• Published in: Chemical engineering science 2001-02, Vol.56 (4), p.1631-1638
• Main Authors: Chiovetta, M.G, Romero, R.L, Cassano, A.E
• Format: Article
• Language: English
• Subjects: Applied sciences; Chemical engineering; Chemistry; Exact sciences and technology; Fluidized bed; General and physical chemistry; General purification processes; Mathematical model; Photocatalytic oxidation; Photocatalytic reactor; Photochemistry; Physical chemistry of induced reactions (with radiations, particles and ultrasonics); Pollution; Reactors; Titanium dioxide; trichloroethylene; Trichloroethylene abatement; Wastewaters; Water treatment and pollution
• ISSN: 0009-2509; 1873-4405
• DOI: 10.1016/S0009-2509(00)00391-2

A system consisting of a fluidized bed of quartz-support particles impregnated with titanium dioxide in a UV-irradiated annular arrangement is presented as an efficient reactor configuration for the photocatalytic oxidation of diluted trichloroethylene in water. A mathematical scheme is developed to analyze the fluidized bed, including a detailed radiation field representation and an intrinsic kinetic scheme. The model is used to predict operating conditions at which good mixing states and fluid renewal rates are accomplished throughout the bed, and to compute contaminant decay. Systems analyzed include a high-pressure Hg lamp, 0.3 m long setup, and an “actinic”, low-pressure lamp in a 1 m long reactor. For relatively high flow rates, per-pass oxidation conversions between 9 and 35% are reached depending on the reactor system considered, and on the titanium oxide concentration in the bed, ranging between 0.1 and 0.5 kg m −3 . Results indicate a strong dependence of reactor performance upon the radiation energy available at each point in the annulus. This availability, in turn, is a fraction of both lamp power and UV-radiation penetration within the bed. For the selected contaminant, the kinetic scheme shows that the low-energy disadvantage in the low-pressure lamp reactor can be compensated by the fact that the radiation field is more evenly distributed throughout the fluidized particle bed.