Direct synthesis of anilines and nitrosobenzenes from phenols

A one-pot synthesis of anilines and nitrosobenzenes from phenols has been developed using an ipso -oxidative aromatic substitution ( i S O Ar) process. The products are obtained in good yields under mild and metal-free conditions. The leaving group effect on reactions that proceed through mixed quio...

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Published in:Organic & biomolecular chemistry 2016-01, Vol.14 (24), p.552-5524
Main Authors: St. Amant, A. H, Frazier, C. P, Newmeyer, B, Fruehauf, K. R, Read de Alaniz, J
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description A one-pot synthesis of anilines and nitrosobenzenes from phenols has been developed using an ipso -oxidative aromatic substitution ( i S O Ar) process. The products are obtained in good yields under mild and metal-free conditions. The leaving group effect on reactions that proceed through mixed quionone monoketals has also been investigated and a predictive model has been established. A one-pot synthesis of anilines and nitrosobenzenes from phenols has been developed using an ipso -oxidative aromatic substitution ( i S O Ar) process.
doi_str_mv 10.1039/c6ob00073h
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title Direct synthesis of anilines and nitrosobenzenes from phenols
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