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Electrochemical performances and gassing behavior of high surface area titanium niobium oxides
A solvothermal synthesis is developed to build a 3D network of nanoparticles, enhancing the electrochemical performances of both TiNb 2 O 7 and Ti 2 Nb 10 O 29 , especially at high current densities, with up to 190 mA h g −1 at 10C. A set of 11 mA h pouch cells combining the nanosized TiNb 2 O 7 wit...
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| Published in: | Journal of materials chemistry. A, Materials for energy and sustainability Materials for energy and sustainability, 2016-01, Vol.4 (29), p.11531-11541 |
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| Main Authors: | , , , , |
| Format: | Article |
| Language: | English |
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| cited_by | cdi_FETCH-LOGICAL-c360t-3f0ebe622b57ea17fecf2d8229307b7cde67ec3d3bea86e92af50116ddda4c213 |
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| cites | cdi_FETCH-LOGICAL-c360t-3f0ebe622b57ea17fecf2d8229307b7cde67ec3d3bea86e92af50116ddda4c213 |
| container_end_page | 11541 |
| container_issue | 29 |
| container_start_page | 11531 |
| container_title | Journal of materials chemistry. A, Materials for energy and sustainability |
| container_volume | 4 |
| creator | Buannic, Lucienne Colin, Jean-François Chapuis, Marlène Chakir, Mohamed Patoux, Sébastien |
| description | A solvothermal synthesis is developed to build a 3D network of nanoparticles, enhancing the electrochemical performances of both TiNb
2
O
7
and Ti
2
Nb
10
O
29
, especially at high current densities, with up to 190 mA h g
−1
at 10C. A set of 11 mA h pouch cells combining the nanosized TiNb
2
O
7
with LiMn
1.5
Ni
0.5
O
4
is tested and is the first to be reported for this material. Soft shell cells are used, not only to evaluate the electrochemical performances of this oxide in a larger scale battery, but also to assess its gassing behavior, a well-known limitation for application of Li
4
Ti
5
O
12
in hybrid electric vehicles. In order to evaluate the sole contribution of TiNb
2
O
7
to the swelling, an additional set of soft shell TiNb
2
O
7
/Li(Ni
1/3
Mn
1/3
Co
1/3
)O
2
cells is assembled and stored at 45 °C in a charged state. A higher swelling behavior is observed for TiNb
2
O
7
in comparison to Li
4
Ti
5
O
12
; a clear trend also appears between the surface area of the oxide and the amount of gassing. The swelling of TiNb
2
O
7
or Ti
2
Nb
10
O
29
based pouch cells should be addressed before further industrial development of the two oxides can be considered.
High surface area TiNb
2
O
7
and Ti
2
Nb
10
O
29
show improved electrochemical performances, however full cell studies indicate a non-negligible gassing behavior. |
| doi_str_mv | 10.1039/c6ta03813a |
| format | article |
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2
O
7
and Ti
2
Nb
10
O
29
, especially at high current densities, with up to 190 mA h g
−1
at 10C. A set of 11 mA h pouch cells combining the nanosized TiNb
2
O
7
with LiMn
1.5
Ni
0.5
O
4
is tested and is the first to be reported for this material. Soft shell cells are used, not only to evaluate the electrochemical performances of this oxide in a larger scale battery, but also to assess its gassing behavior, a well-known limitation for application of Li
4
Ti
5
O
12
in hybrid electric vehicles. In order to evaluate the sole contribution of TiNb
2
O
7
to the swelling, an additional set of soft shell TiNb
2
O
7
/Li(Ni
1/3
Mn
1/3
Co
1/3
)O
2
cells is assembled and stored at 45 °C in a charged state. A higher swelling behavior is observed for TiNb
2
O
7
in comparison to Li
4
Ti
5
O
12
; a clear trend also appears between the surface area of the oxide and the amount of gassing. The swelling of TiNb
2
O
7
or Ti
2
Nb
10
O
29
based pouch cells should be addressed before further industrial development of the two oxides can be considered.
High surface area TiNb
2
O
7
and Ti
2
Nb
10
O
29
show improved electrochemical performances, however full cell studies indicate a non-negligible gassing behavior.</description><identifier>ISSN: 2050-7488</identifier><identifier>EISSN: 2050-7496</identifier><identifier>DOI: 10.1039/c6ta03813a</identifier><language>eng</language><subject>Construction ; Industrial development ; Nanostructure ; Networks ; Oxides ; Pouches ; Surface area ; Swelling</subject><ispartof>Journal of materials chemistry. A, Materials for energy and sustainability, 2016-01, Vol.4 (29), p.11531-11541</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c360t-3f0ebe622b57ea17fecf2d8229307b7cde67ec3d3bea86e92af50116ddda4c213</citedby><cites>FETCH-LOGICAL-c360t-3f0ebe622b57ea17fecf2d8229307b7cde67ec3d3bea86e92af50116ddda4c213</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Buannic, Lucienne</creatorcontrib><creatorcontrib>Colin, Jean-François</creatorcontrib><creatorcontrib>Chapuis, Marlène</creatorcontrib><creatorcontrib>Chakir, Mohamed</creatorcontrib><creatorcontrib>Patoux, Sébastien</creatorcontrib><title>Electrochemical performances and gassing behavior of high surface area titanium niobium oxides</title><title>Journal of materials chemistry. A, Materials for energy and sustainability</title><description>A solvothermal synthesis is developed to build a 3D network of nanoparticles, enhancing the electrochemical performances of both TiNb
2
O
7
and Ti
2
Nb
10
O
29
, especially at high current densities, with up to 190 mA h g
−1
at 10C. A set of 11 mA h pouch cells combining the nanosized TiNb
2
O
7
with LiMn
1.5
Ni
0.5
O
4
is tested and is the first to be reported for this material. Soft shell cells are used, not only to evaluate the electrochemical performances of this oxide in a larger scale battery, but also to assess its gassing behavior, a well-known limitation for application of Li
4
Ti
5
O
12
in hybrid electric vehicles. In order to evaluate the sole contribution of TiNb
2
O
7
to the swelling, an additional set of soft shell TiNb
2
O
7
/Li(Ni
1/3
Mn
1/3
Co
1/3
)O
2
cells is assembled and stored at 45 °C in a charged state. A higher swelling behavior is observed for TiNb
2
O
7
in comparison to Li
4
Ti
5
O
12
; a clear trend also appears between the surface area of the oxide and the amount of gassing. The swelling of TiNb
2
O
7
or Ti
2
Nb
10
O
29
based pouch cells should be addressed before further industrial development of the two oxides can be considered.
High surface area TiNb
2
O
7
and Ti
2
Nb
10
O
29
show improved electrochemical performances, however full cell studies indicate a non-negligible gassing behavior.</description><subject>Construction</subject><subject>Industrial development</subject><subject>Nanostructure</subject><subject>Networks</subject><subject>Oxides</subject><subject>Pouches</subject><subject>Surface area</subject><subject>Swelling</subject><issn>2050-7488</issn><issn>2050-7496</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2016</creationdate><recordtype>article</recordtype><recordid>eNqN0T1PwzAQBmALgURVurAjeURIAX80tjNWVfmQKrGUlejinFujJC52guDf01JUVm55b3h0w3uEXHJ2y5ks7qzqgUnDJZyQkWA5y_S0UKfH3ZhzMknpje3GMKaKYkReFw3aPga7wdZbaOgWowuxhc5iotDVdA0p-W5NK9zAhw-RBkc3fr2haYgOLFKICLT3PXR-aGnnQ7XP8OlrTBfkzEGTcPKbY_Jyv1jNH7Pl88PTfLbMrFSsz6RjWKESoso1AtcOrRO1EaKQTFfa1qg0WlnLCsEoLAS4nHGu6rqGqRVcjsn14e42hvcBU1-2PllsGugwDKnkRuZKmGmu_0GZ0ULJQu3ozYHaGFKK6Mpt9C3Er5Kzcl95OVer2U_lsx2-OuCY7NH9vUR-A8Kofxo</recordid><startdate>20160101</startdate><enddate>20160101</enddate><creator>Buannic, Lucienne</creator><creator>Colin, Jean-François</creator><creator>Chapuis, Marlène</creator><creator>Chakir, Mohamed</creator><creator>Patoux, Sébastien</creator><scope>AAYXX</scope><scope>CITATION</scope><scope>7ST</scope><scope>C1K</scope><scope>SOI</scope><scope>7SP</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope></search><sort><creationdate>20160101</creationdate><title>Electrochemical performances and gassing behavior of high surface area titanium niobium oxides</title><author>Buannic, Lucienne ; Colin, Jean-François ; Chapuis, Marlène ; Chakir, Mohamed ; Patoux, Sébastien</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c360t-3f0ebe622b57ea17fecf2d8229307b7cde67ec3d3bea86e92af50116ddda4c213</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2016</creationdate><topic>Construction</topic><topic>Industrial development</topic><topic>Nanostructure</topic><topic>Networks</topic><topic>Oxides</topic><topic>Pouches</topic><topic>Surface area</topic><topic>Swelling</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Buannic, Lucienne</creatorcontrib><creatorcontrib>Colin, Jean-François</creatorcontrib><creatorcontrib>Chapuis, Marlène</creatorcontrib><creatorcontrib>Chakir, Mohamed</creatorcontrib><creatorcontrib>Patoux, Sébastien</creatorcontrib><collection>CrossRef</collection><collection>Environment Abstracts</collection><collection>Environmental Sciences and Pollution Management</collection><collection>Environment Abstracts</collection><collection>Electronics & Communications Abstracts</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Journal of materials chemistry. A, Materials for energy and sustainability</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Buannic, Lucienne</au><au>Colin, Jean-François</au><au>Chapuis, Marlène</au><au>Chakir, Mohamed</au><au>Patoux, Sébastien</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Electrochemical performances and gassing behavior of high surface area titanium niobium oxides</atitle><jtitle>Journal of materials chemistry. A, Materials for energy and sustainability</jtitle><date>2016-01-01</date><risdate>2016</risdate><volume>4</volume><issue>29</issue><spage>11531</spage><epage>11541</epage><pages>11531-11541</pages><issn>2050-7488</issn><eissn>2050-7496</eissn><abstract>A solvothermal synthesis is developed to build a 3D network of nanoparticles, enhancing the electrochemical performances of both TiNb
2
O
7
and Ti
2
Nb
10
O
29
, especially at high current densities, with up to 190 mA h g
−1
at 10C. A set of 11 mA h pouch cells combining the nanosized TiNb
2
O
7
with LiMn
1.5
Ni
0.5
O
4
is tested and is the first to be reported for this material. Soft shell cells are used, not only to evaluate the electrochemical performances of this oxide in a larger scale battery, but also to assess its gassing behavior, a well-known limitation for application of Li
4
Ti
5
O
12
in hybrid electric vehicles. In order to evaluate the sole contribution of TiNb
2
O
7
to the swelling, an additional set of soft shell TiNb
2
O
7
/Li(Ni
1/3
Mn
1/3
Co
1/3
)O
2
cells is assembled and stored at 45 °C in a charged state. A higher swelling behavior is observed for TiNb
2
O
7
in comparison to Li
4
Ti
5
O
12
; a clear trend also appears between the surface area of the oxide and the amount of gassing. The swelling of TiNb
2
O
7
or Ti
2
Nb
10
O
29
based pouch cells should be addressed before further industrial development of the two oxides can be considered.
High surface area TiNb
2
O
7
and Ti
2
Nb
10
O
29
show improved electrochemical performances, however full cell studies indicate a non-negligible gassing behavior.</abstract><doi>10.1039/c6ta03813a</doi><tpages>11</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 2050-7488 |
| ispartof | Journal of materials chemistry. A, Materials for energy and sustainability, 2016-01, Vol.4 (29), p.11531-11541 |
| issn | 2050-7488 2050-7496 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_1808726396 |
| source | Royal Society of Chemistry:Jisc Collections:Royal Society of Chemistry Read and Publish 2022-2024 (reading list) |
| subjects | Construction Industrial development Nanostructure Networks Oxides Pouches Surface area Swelling |
| title | Electrochemical performances and gassing behavior of high surface area titanium niobium oxides |
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