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A Fluorescent Sensor for Al(III) and Colorimetric Sensor for Fe(III) and Fe(II) Based on a Novel 8-Hydroxyquinoline Derivative
A novel 8-hydroxyquinoline-based fluorescent and colorimetric chemosensor was designed, synthesized and fully characterized. The sensor showed high selectivity and sensitivity toward Al 3+ over other tested cations in EtOH/H 2 O (1:99, v /v) medium. The increase in fluorescence intensity was linearl...
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| Published in: | Journal of fluorescence 2016-09, Vol.26 (5), p.1885-1894 |
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| Main Authors: | , , |
| Format: | Article |
| Language: | English |
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| cited_by | cdi_FETCH-LOGICAL-c372t-396598f54ef7c1d9f52bee3758ccb9da351ba455584c6cea616d11d8b29a2f3f3 |
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| cites | cdi_FETCH-LOGICAL-c372t-396598f54ef7c1d9f52bee3758ccb9da351ba455584c6cea616d11d8b29a2f3f3 |
| container_end_page | 1894 |
| container_issue | 5 |
| container_start_page | 1885 |
| container_title | Journal of fluorescence |
| container_volume | 26 |
| creator | Lashgari, Negar Badiei, Alireza Mohammadi Ziarani, Ghodsi |
| description | A novel 8-hydroxyquinoline-based fluorescent and colorimetric chemosensor was designed, synthesized and fully characterized. The sensor showed high selectivity and sensitivity toward Al
3+
over other tested cations in EtOH/H
2
O (1:99,
v
/v) medium. The increase in fluorescence intensity was linearly proportional to the concentration of Al
3+
with a detection limit of 7.38 × 10
−6
M. Moreover, the sensor exhibited an obvious color change from yellow to black in the presence of Fe
2+
and Fe
3+
in EtOH/THF (99:1,
v
/v) solution. The absorbance changes showed a linear response to iron ions with the detection limits of 4.24 × 10
−7
M and 5.60 × 10
−7
M for Fe
2+
and Fe
3+
, respectively. Thus, this chemosensor provides a novel approach for selectively recognition of Al
3+
, Fe
3+
and Fe
2+
among environmentally relevant metal ions. |
| doi_str_mv | 10.1007/s10895-016-1883-3 |
| format | article |
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3+
over other tested cations in EtOH/H
2
O (1:99,
v
/v) medium. The increase in fluorescence intensity was linearly proportional to the concentration of Al
3+
with a detection limit of 7.38 × 10
−6
M. Moreover, the sensor exhibited an obvious color change from yellow to black in the presence of Fe
2+
and Fe
3+
in EtOH/THF (99:1,
v
/v) solution. The absorbance changes showed a linear response to iron ions with the detection limits of 4.24 × 10
−7
M and 5.60 × 10
−7
M for Fe
2+
and Fe
3+
, respectively. Thus, this chemosensor provides a novel approach for selectively recognition of Al
3+
, Fe
3+
and Fe
2+
among environmentally relevant metal ions.</description><identifier>ISSN: 1053-0509</identifier><identifier>EISSN: 1573-4994</identifier><identifier>DOI: 10.1007/s10895-016-1883-3</identifier><identifier>PMID: 27444961</identifier><language>eng</language><publisher>New York: Springer US</publisher><subject>Analytical Chemistry ; Biochemistry ; Biological and Medical Physics ; Biomedical and Life Sciences ; Biomedicine ; Biophysics ; Biotechnology ; Chemical sensors ; Chemoreceptors ; Colorimetry ; Ferric ions ; Ferrous ions ; Fluorescence ; Hydroxyquinoline ; Iron ; Original Article</subject><ispartof>Journal of fluorescence, 2016-09, Vol.26 (5), p.1885-1894</ispartof><rights>Springer Science+Business Media New York 2016</rights><rights>Copyright Springer Science & Business Media 2016</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c372t-396598f54ef7c1d9f52bee3758ccb9da351ba455584c6cea616d11d8b29a2f3f3</citedby><cites>FETCH-LOGICAL-c372t-396598f54ef7c1d9f52bee3758ccb9da351ba455584c6cea616d11d8b29a2f3f3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27923,27924</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/27444961$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Lashgari, Negar</creatorcontrib><creatorcontrib>Badiei, Alireza</creatorcontrib><creatorcontrib>Mohammadi Ziarani, Ghodsi</creatorcontrib><title>A Fluorescent Sensor for Al(III) and Colorimetric Sensor for Fe(III) and Fe(II) Based on a Novel 8-Hydroxyquinoline Derivative</title><title>Journal of fluorescence</title><addtitle>J Fluoresc</addtitle><addtitle>J Fluoresc</addtitle><description>A novel 8-hydroxyquinoline-based fluorescent and colorimetric chemosensor was designed, synthesized and fully characterized. The sensor showed high selectivity and sensitivity toward Al
3+
over other tested cations in EtOH/H
2
O (1:99,
v
/v) medium. The increase in fluorescence intensity was linearly proportional to the concentration of Al
3+
with a detection limit of 7.38 × 10
−6
M. Moreover, the sensor exhibited an obvious color change from yellow to black in the presence of Fe
2+
and Fe
3+
in EtOH/THF (99:1,
v
/v) solution. The absorbance changes showed a linear response to iron ions with the detection limits of 4.24 × 10
−7
M and 5.60 × 10
−7
M for Fe
2+
and Fe
3+
, respectively. Thus, this chemosensor provides a novel approach for selectively recognition of Al
3+
, Fe
3+
and Fe
2+
among environmentally relevant metal ions.</description><subject>Analytical Chemistry</subject><subject>Biochemistry</subject><subject>Biological and Medical Physics</subject><subject>Biomedical and Life Sciences</subject><subject>Biomedicine</subject><subject>Biophysics</subject><subject>Biotechnology</subject><subject>Chemical sensors</subject><subject>Chemoreceptors</subject><subject>Colorimetry</subject><subject>Ferric ions</subject><subject>Ferrous ions</subject><subject>Fluorescence</subject><subject>Hydroxyquinoline</subject><subject>Iron</subject><subject>Original Article</subject><issn>1053-0509</issn><issn>1573-4994</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2016</creationdate><recordtype>article</recordtype><recordid>eNp1kU1v1DAQhi1ERT_gB3BBlri0BxePPxL7uN126UoVHIBz5DgTlCprt3ayYi_89rpsgQqJg-WR5nlfe-Yl5C3wc-C8_pCBG6sZh4qBMZLJF-QIdC2Zsla9LDXXknHN7SE5zvmWc26NMq_IoaiVUraCI_JzQVfjHBNmj2GiXzDkmGhfzmI8Xa_XZ9SFji7jGNOwwSkN_jmzwr_Mr_qMXriMHY2BOvopbnGkhl3vuhR_7O7nIcRxCEgvMQ1bNw1bfE0OejdmfPN0n5Bvq6uvy2t28_njerm4YV7WYmLSVtqaXivsaw-d7bVoEWWtjfet7ZzU0DqltTbKVx5dBVUH0JlWWCd62csTcrr3vUvxfsY8NZuhTDyOLmCccwMGhBBK6aqg7_9Bb-OcQvldoQwve65BFQr2lE8x54R9c1cW5NKuAd48htPsw2lKOI862ciieffkPLcb7P4ofqdRALEHcmmF75iePf1f1wfDSZfK</recordid><startdate>20160901</startdate><enddate>20160901</enddate><creator>Lashgari, Negar</creator><creator>Badiei, Alireza</creator><creator>Mohammadi Ziarani, Ghodsi</creator><general>Springer US</general><general>Springer Nature B.V</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope></search><sort><creationdate>20160901</creationdate><title>A Fluorescent Sensor for Al(III) and Colorimetric Sensor for Fe(III) and Fe(II) Based on a Novel 8-Hydroxyquinoline Derivative</title><author>Lashgari, Negar ; Badiei, Alireza ; Mohammadi Ziarani, Ghodsi</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c372t-396598f54ef7c1d9f52bee3758ccb9da351ba455584c6cea616d11d8b29a2f3f3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2016</creationdate><topic>Analytical Chemistry</topic><topic>Biochemistry</topic><topic>Biological and Medical Physics</topic><topic>Biomedical and Life Sciences</topic><topic>Biomedicine</topic><topic>Biophysics</topic><topic>Biotechnology</topic><topic>Chemical sensors</topic><topic>Chemoreceptors</topic><topic>Colorimetry</topic><topic>Ferric ions</topic><topic>Ferrous ions</topic><topic>Fluorescence</topic><topic>Hydroxyquinoline</topic><topic>Iron</topic><topic>Original Article</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Lashgari, Negar</creatorcontrib><creatorcontrib>Badiei, Alireza</creatorcontrib><creatorcontrib>Mohammadi Ziarani, Ghodsi</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><jtitle>Journal of fluorescence</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Lashgari, Negar</au><au>Badiei, Alireza</au><au>Mohammadi Ziarani, Ghodsi</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>A Fluorescent Sensor for Al(III) and Colorimetric Sensor for Fe(III) and Fe(II) Based on a Novel 8-Hydroxyquinoline Derivative</atitle><jtitle>Journal of fluorescence</jtitle><stitle>J Fluoresc</stitle><addtitle>J Fluoresc</addtitle><date>2016-09-01</date><risdate>2016</risdate><volume>26</volume><issue>5</issue><spage>1885</spage><epage>1894</epage><pages>1885-1894</pages><issn>1053-0509</issn><eissn>1573-4994</eissn><abstract>A novel 8-hydroxyquinoline-based fluorescent and colorimetric chemosensor was designed, synthesized and fully characterized. The sensor showed high selectivity and sensitivity toward Al
3+
over other tested cations in EtOH/H
2
O (1:99,
v
/v) medium. The increase in fluorescence intensity was linearly proportional to the concentration of Al
3+
with a detection limit of 7.38 × 10
−6
M. Moreover, the sensor exhibited an obvious color change from yellow to black in the presence of Fe
2+
and Fe
3+
in EtOH/THF (99:1,
v
/v) solution. The absorbance changes showed a linear response to iron ions with the detection limits of 4.24 × 10
−7
M and 5.60 × 10
−7
M for Fe
2+
and Fe
3+
, respectively. Thus, this chemosensor provides a novel approach for selectively recognition of Al
3+
, Fe
3+
and Fe
2+
among environmentally relevant metal ions.</abstract><cop>New York</cop><pub>Springer US</pub><pmid>27444961</pmid><doi>10.1007/s10895-016-1883-3</doi><tpages>10</tpages></addata></record> |
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| subjects | Analytical Chemistry Biochemistry Biological and Medical Physics Biomedical and Life Sciences Biomedicine Biophysics Biotechnology Chemical sensors Chemoreceptors Colorimetry Ferric ions Ferrous ions Fluorescence Hydroxyquinoline Iron Original Article |
| title | A Fluorescent Sensor for Al(III) and Colorimetric Sensor for Fe(III) and Fe(II) Based on a Novel 8-Hydroxyquinoline Derivative |
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