Soluble Metal-Nanoparticle-Decorated Porous Coordination Polymers for the Homogenization of Heterogeneous Catalysis

Ultrasmall metal nanoparticles (MNPs) were decorated on soluble porous coordination polymers (PCPs) with high metal loadings. The solubility of the composite and the size of the MNPs can be controlled by varying the ratio of the precursors to the supports. The soluble PCPs can serve as a platform to...

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Bibliographic Details
Published in:Journal of the American Chemical Society 2016-08, Vol.138 (32), p.10104-10107
Main Authors: Huang, Yuan-Biao, Wang, Qiang, Liang, Jun, Wang, Xusheng, Cao, Rong
Format: Article
Language:English
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Summary:Ultrasmall metal nanoparticles (MNPs) were decorated on soluble porous coordination polymers (PCPs) with high metal loadings. The solubility of the composite and the size of the MNPs can be controlled by varying the ratio of the precursors to the supports. The soluble PCPs can serve as a platform to homogenize heterogeneous MNPs catalysts, which exhibited excellent activity and recyclability in C–H activation and Suzuki reactions. This strategy combines the advantages of homogeneous and heterogeneous catalysis and may bring new inspiration to catalysis.
ISSN:0002-7863
1520-5126
DOI:10.1021/jacs.6b06185