Diboron(4) Compounds: From Structural Curiosity to Synthetic Workhorse

Although known for over 90 years, only in the past two decades has the chemistry of diboron(4) compounds been extensively explored. Many interesting structural features and reaction patterns have emerged, and more importantly, these compounds now feature prominently in both metal-catalyzed and metal...

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Published in:Chemical reviews 2016-08, Vol.116 (16), p.9091-9161
Main Authors: Neeve, Emily C, Geier, Stephen J, Mkhalid, Ibraheem A. I, Westcott, Stephen A, Marder, Todd B
Format: Article
Language:English
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Chemical bonds
Chemical compounds
Chemical reactions
Chemistry
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description Although known for over 90 years, only in the past two decades has the chemistry of diboron(4) compounds been extensively explored. Many interesting structural features and reaction patterns have emerged, and more importantly, these compounds now feature prominently in both metal-catalyzed and metal-free methodologies for the formation of B–C bonds and other processes.
doi_str_mv 10.1021/acs.chemrev.6b00193
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source American Chemical Society:Jisc Collections:American Chemical Society Read & Publish Agreement 2022-2024 (Reading list)
subjects Chemical bonds
Chemical compounds
Chemical reactions
Chemistry
title Diboron(4) Compounds: From Structural Curiosity to Synthetic Workhorse
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