Numerical model of Zeeman splitting of ro-vibrational lines in the fundamental band of NO molecule

This paper presents the results of calculation the LMR spectrograms of NO molecule in a variable magnetic field with maximum induction up to 6T for probed CO laser lines. For the simulation of the LMR spectrum a numerical model was developed. This model is based on the numerical diagonalization the...

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Bibliographic Details
Published in:Journal of quantitative spectroscopy & radiative transfer 2016-07, Vol.177, p.216-224
Main Authors: Borkov, Yu.G., Sulakshina, O.N., Klimachev, Yu.M.
Format: Article
Language:English
Subjects:
Absorption
CO laser
Laser magnetic resonance spectroscopy
Lasers
Magnetic fields
Magnetic induction
Mathematical models
Nitric oxide
Radiative transfer
Spectrograms
Splitting
Zeeman effect
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Summary:This paper presents the results of calculation the LMR spectrograms of NO molecule in a variable magnetic field with maximum induction up to 6T for probed CO laser lines. For the simulation of the LMR spectrum a numerical model was developed. This model is based on the numerical diagonalization the matrix of the effective molecular Hamiltonian, which includes Zeeman operator corresponding to interaction an external magnetic field with NO molecule. The comparison of calculated and experimental spectrograms has shown that the numerical model is very reliable and can reproduce the location of absorption peaks measured in a damped oscillating magnetic field. •Simulation of the LMR spectrograms of NO molecule in a strong variable magnetic field.
ISSN:0022-4073
1879-1352
DOI:10.1016/j.jqsrt.2015.12.006