A C sub(60)-aryne building block: synthesis of a hybrid all-carbon nanostructure

The synthesis of a [60]fullerene-benzyne building block and its further chemical cycloaddition reaction with graphene has resulted in a new all-carbon hybrid material which has been characterized by TGA, FTIR and Raman spectroscopies, XPS as well as AFM and TEM. Based on computational studies, the f...

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Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2016-05, Vol.52 (40), p.6677-6680
Main Authors: Garcia, D, Rodriguez-Perez, L, Herranz, MA, Pena, D, Guitian, E, Bailey, S, Al-Galiby, Q, Noori, M, Lambert, C J, Perez, D, Martin, N
Format: Article
Language:English
Subjects:
Chemical reactions
Formations
Fourier transforms
Graphene
Infrared spectroscopy
Nanostructure
Synthesis
X-ray photoelectron spectroscopy
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Summary:The synthesis of a [60]fullerene-benzyne building block and its further chemical cycloaddition reaction with graphene has resulted in a new all-carbon hybrid material which has been characterized by TGA, FTIR and Raman spectroscopies, XPS as well as AFM and TEM. Based on computational studies, the formation of both [2+2] and [4+2] cycloadducts on the graphene surface is feasible.
ISSN:1359-7345
1364-548X
DOI:10.1039/c5cc10462a