BINOL diesters as useful building blocks towards chiral macrocyclic compounds

Double-amidation reaction of (R)- or (S)-2,2′-([1,1′-binaphthalene]-2,2′-diylbis(oxy))diacetic dimethyl ester with five differing in length α,ω-diaminoethers were used for the synthesis of chiral macrocyclic compounds of different size of the cavity, potential receptors of various chiral guests. [Di...

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Bibliographic Details
Published in:Tetrahedron 2016-04, Vol.72 (16), p.1928-1932
Main Authors: Pikus, Grzegorz, Jurczak, Janusz
Format: Article
Language:English
Subjects:
BINOL
Chirality
Diesters
Dimethyl
Double-amidation reaction
Esters
Holes
Macrocyclic amides
Macrocyclic compounds
Receptors
Static combinatorial libraries
Synthesis (chemistry)
Tetrahedrons
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Summary:Double-amidation reaction of (R)- or (S)-2,2′-([1,1′-binaphthalene]-2,2′-diylbis(oxy))diacetic dimethyl ester with five differing in length α,ω-diaminoethers were used for the synthesis of chiral macrocyclic compounds of different size of the cavity, potential receptors of various chiral guests. [Display omitted]
ISSN:0040-4020
1464-5416
DOI:10.1016/j.tet.2016.02.051