Disulfide-based metal-free α-sulfanylation of ketones

An eco-friendly methodology for the direct α-sulfanylation of ketones, has been developed. The procedure, based on the use of functionalized diaryldisulfides and catalyzed by d , l -proline, represents a mild and efficient approach for the preparation of α-arylthio-ketones.

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Bibliographic Details
Published in:RSC advances 2015-01, Vol.5 (117), p.96695-96704
Main Authors: Vaquer, Andrea F., Frongia, Angelo, Secci, Francesco, Tuveri, Enrica
Format: Article
Language:English
Subjects:
Ketones
Methodology
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Description
Summary:An eco-friendly methodology for the direct α-sulfanylation of ketones, has been developed. The procedure, based on the use of functionalized diaryldisulfides and catalyzed by d , l -proline, represents a mild and efficient approach for the preparation of α-arylthio-ketones.
ISSN:2046-2069
2046-2069
DOI:10.1039/C5RA17913K