Annular reactor testing and Raman surface characterization of the CPO of i-octane and n-octane on Rh based catalyst

•Kinetic schemes are developed for the CPO of n-octane and i-octane over Rh.•The role of C-species is investigated by combining kinetic tests and Raman measurements.•The rate of oxidation follows the order: CH4≪C3H8≅i-C8H18

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Bibliographic Details
Published in:Chemical engineering journal (Lausanne, Switzerland : 1996) Switzerland : 1996), 2016-06, Vol.294, p.9-21
Main Authors: Pagani, Davide, da Silva, Roberto Batista, Moioli, Emanuele, Donazzi, Alessandro, Lucotti, Andrea, Tommasini, Matteo, Castiglioni, Chiara, Brandao, Soraia Teixeira, Beretta, Alessandra, Groppi, Gianpiero
Format: Article
Language:English
Subjects:
Annular
Annular reactor
Catalysts
Formations
Hydrocarbons
Hydrogen
i-Octane
n-Octane
Oxidation
Raman characterization
Reaction kinetics
Reactors
Reforming
Rhodium
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Description
Summary:•Kinetic schemes are developed for the CPO of n-octane and i-octane over Rh.•The role of C-species is investigated by combining kinetic tests and Raman measurements.•The rate of oxidation follows the order: CH4≪C3H8≅i-C8H18
ISSN:1385-8947
1873-3212
DOI:10.1016/j.cej.2016.02.090