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A Nanomesoporous Catalyst from Modified Red Mud and Its Application for Methane Decomposition to Hydrogen Production
A type of nanomesoporous modified red mud (MRM) catalyst was prepared and utilized for catalytic methane decomposition (CMD) to produce hydrogen. The modification process significantly simplified the mineral composition of the red mud (RM); in the meantime, the physical and chemical structure of RM...
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Published in: | Journal of nanomaterials 2016-01, Vol.2016 (2016), p.1-8 |
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creator | Li, Fenghai Li, Haipeng Li, Peng Liu, Quanrun Fang, Xiaoke Huang, Guangxu |
description | A type of nanomesoporous modified red mud (MRM) catalyst was prepared and utilized for catalytic methane decomposition (CMD) to produce hydrogen. The modification process significantly simplified the mineral composition of the red mud (RM); in the meantime, the physical and chemical structure of RM was changed. TEM images suggested that MRM was a kind of nanomesoporous material assembled by a number of uniformly nanoscale particles, BET results showed that the pore size distributions of MRM were ranged from 3 to 12 nm, and the specific surface area and total pore volumes of red mud improved from 8.00 m2/g and 0.08 cm3/g to 190.61 m2/g and 0.39 cm3/g, respectively. The catalytic performance of the catalysts has been tested at 800°C; the results showed that MRM exhibited much higher activity and stability than RM for CMD. |
doi_str_mv | 10.1155/2016/6947636 |
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The modification process significantly simplified the mineral composition of the red mud (RM); in the meantime, the physical and chemical structure of RM was changed. TEM images suggested that MRM was a kind of nanomesoporous material assembled by a number of uniformly nanoscale particles, BET results showed that the pore size distributions of MRM were ranged from 3 to 12 nm, and the specific surface area and total pore volumes of red mud improved from 8.00 m2/g and 0.08 cm3/g to 190.61 m2/g and 0.39 cm3/g, respectively. The catalytic performance of the catalysts has been tested at 800°C; the results showed that MRM exhibited much higher activity and stability than RM for CMD.</description><identifier>ISSN: 1687-4110</identifier><identifier>EISSN: 1687-4129</identifier><identifier>DOI: 10.1155/2016/6947636</identifier><language>eng</language><publisher>Cairo, Egypt: Hindawi Publishing Corporation</publisher><subject>Aluminum ; Carbon ; Catalysis ; Catalysts ; Climate change ; Decomposition ; Methane ; Morphology ; Nanomaterials ; Nanostructure ; Porosity ; Red mud</subject><ispartof>Journal of nanomaterials, 2016-01, Vol.2016 (2016), p.1-8</ispartof><rights>Copyright © 2016 Xiaoke Fang et al.</rights><rights>Copyright © 2016 Xiaoke Fang et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-a503t-a48a59d11ec127cb9a22bb4ddbc59b62ec7b9eff9f1389e8de81c62aa76ab2043</citedby><cites>FETCH-LOGICAL-a503t-a48a59d11ec127cb9a22bb4ddbc59b62ec7b9eff9f1389e8de81c62aa76ab2043</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://www.proquest.com/docview/1785755290/fulltextPDF?pq-origsite=primo$$EPDF$$P50$$Gproquest$$Hfree_for_read</linktopdf><linktohtml>$$Uhttps://www.proquest.com/docview/1785755290?pq-origsite=primo$$EHTML$$P50$$Gproquest$$Hfree_for_read</linktohtml><link.rule.ids>314,777,781,25734,27905,27906,36993,36994,44571,74875</link.rule.ids></links><search><contributor>Kochuveedu, Saji T.</contributor><creatorcontrib>Li, Fenghai</creatorcontrib><creatorcontrib>Li, Haipeng</creatorcontrib><creatorcontrib>Li, Peng</creatorcontrib><creatorcontrib>Liu, Quanrun</creatorcontrib><creatorcontrib>Fang, Xiaoke</creatorcontrib><creatorcontrib>Huang, Guangxu</creatorcontrib><title>A Nanomesoporous Catalyst from Modified Red Mud and Its Application for Methane Decomposition to Hydrogen Production</title><title>Journal of nanomaterials</title><description>A type of nanomesoporous modified red mud (MRM) catalyst was prepared and utilized for catalytic methane decomposition (CMD) to produce hydrogen. The modification process significantly simplified the mineral composition of the red mud (RM); in the meantime, the physical and chemical structure of RM was changed. TEM images suggested that MRM was a kind of nanomesoporous material assembled by a number of uniformly nanoscale particles, BET results showed that the pore size distributions of MRM were ranged from 3 to 12 nm, and the specific surface area and total pore volumes of red mud improved from 8.00 m2/g and 0.08 cm3/g to 190.61 m2/g and 0.39 cm3/g, respectively. The catalytic performance of the catalysts has been tested at 800°C; the results showed that MRM exhibited much higher activity and stability than RM for CMD.</description><subject>Aluminum</subject><subject>Carbon</subject><subject>Catalysis</subject><subject>Catalysts</subject><subject>Climate change</subject><subject>Decomposition</subject><subject>Methane</subject><subject>Morphology</subject><subject>Nanomaterials</subject><subject>Nanostructure</subject><subject>Porosity</subject><subject>Red mud</subject><issn>1687-4110</issn><issn>1687-4129</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2016</creationdate><recordtype>article</recordtype><sourceid>PIMPY</sourceid><recordid>eNqF0UFrFTEQB_BFFKytN88S8CLU12aym-zm-HhtbaFPRdrzMptMbMruZk2yyPv23ecrCl48hAkzP8KEf1G8A34GIOW54KDOla5qVaoXxRGopl5VIPTLP3fgr4s3KT1yXkktxVGR1-wLjmGgFKYQw5zYBjP2u5SZi2Fg22C982TZ9-VsZ8twtOwmJ7aept4bzD6MzIXItpQfcCR2QSYMU0j-9yQHdr2zMfygkX2Lwc5m3z4pXjnsE719rsfF_dXl3eZ6dfv1881mfbtCycu8wqpBqS0AGRC16TQK0XWVtZ2RulOCTN1pck47KBtNjaUGjBKItcJO8Ko8Lj4e3p1i-DlTyu3gk6G-XxZdvtpCA4pLXelyoR_-oY9hjuOyXQt1I2spheaL-nRQJoaUIrl2in7AuGuBt_sI2n0E7XMECz898Ac_Wvzl_6ffHzQthhz-1cB1KXT5BHQxkRA</recordid><startdate>20160101</startdate><enddate>20160101</enddate><creator>Li, Fenghai</creator><creator>Li, Haipeng</creator><creator>Li, Peng</creator><creator>Liu, Quanrun</creator><creator>Fang, Xiaoke</creator><creator>Huang, Guangxu</creator><general>Hindawi Publishing Corporation</general><general>Hindawi Limited</general><scope>ADJCN</scope><scope>AHFXO</scope><scope>RHU</scope><scope>RHW</scope><scope>RHX</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>ABUWG</scope><scope>AFKRA</scope><scope>AZQEC</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>CWDGH</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>JG9</scope><scope>KB.</scope><scope>L7M</scope><scope>PDBOC</scope><scope>PIMPY</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope><scope>F28</scope><scope>FR3</scope></search><sort><creationdate>20160101</creationdate><title>A Nanomesoporous Catalyst from Modified Red Mud and Its Application for Methane Decomposition to Hydrogen Production</title><author>Li, Fenghai ; 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The modification process significantly simplified the mineral composition of the red mud (RM); in the meantime, the physical and chemical structure of RM was changed. TEM images suggested that MRM was a kind of nanomesoporous material assembled by a number of uniformly nanoscale particles, BET results showed that the pore size distributions of MRM were ranged from 3 to 12 nm, and the specific surface area and total pore volumes of red mud improved from 8.00 m2/g and 0.08 cm3/g to 190.61 m2/g and 0.39 cm3/g, respectively. The catalytic performance of the catalysts has been tested at 800°C; the results showed that MRM exhibited much higher activity and stability than RM for CMD.</abstract><cop>Cairo, Egypt</cop><pub>Hindawi Publishing Corporation</pub><doi>10.1155/2016/6947636</doi><tpages>8</tpages><oa>free_for_read</oa></addata></record> |
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subjects | Aluminum Carbon Catalysis Catalysts Climate change Decomposition Methane Morphology Nanomaterials Nanostructure Porosity Red mud |
title | A Nanomesoporous Catalyst from Modified Red Mud and Its Application for Methane Decomposition to Hydrogen Production |
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