A new cycloadduct based on quadricyclane and perfluorocyclohexene: synthesis, metathesis polymerization and gas-transport properties of the obtained polymer

A new fluorine-containing tricyclononene was synthesized by [2σ + 2σ + 2π]-cycloaddition of quadricyclane with perfluorocyclohexene. This cycloadduct was subjected to ring-opening metathesis polymerization. Gas-transport properties of the obtained polymer were estimated.

Saved in:
Bibliographic Details
Published in:Mendeleev communications 2016-03, Vol.26 (2), p.124-126
Main Authors: Borisov, Ilya L., Akmalov, Timur R., Ivanov, Andrey O., Volkov, Vladimir V., Finkelshtein, Eugene Sh, Bermeshev, Maxim V.
Format: Article
Language:English
Subjects:
Decomposition reactions
Metathesis
Polymerization
Synthesis
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:A new fluorine-containing tricyclononene was synthesized by [2σ + 2σ + 2π]-cycloaddition of quadricyclane with perfluorocyclohexene. This cycloadduct was subjected to ring-opening metathesis polymerization. Gas-transport properties of the obtained polymer were estimated.
ISSN:0959-9436
DOI:10.1016/j.mencom.2016.03.013