Preparation of Organic Nitrates from Alcohols and N sub(2)O sub(5) for Species Identification in Atmospheric Samples

The laboratory synthesis of mono- and bifunctional organic nitrates from the reaction of alcohols and dinitrogen pentoxide is described. The preparation of the organic nitrates was performed in an all-glass vacuum line with Teflon stopcocks to which three traps for N sub(2)O sub(5), alcohol, and the...

Full description

Saved in:
Bibliographic Details
Published in:Journal of atmospheric chemistry 1993-01, Vol.16 (4), p.349-359
Main Authors: Kames, J, Schurath, U, Flocke, F, Volz-Thomas, A
Format: Article
Language:English
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
cited_by
cites
container_end_page 359
container_issue 4
container_start_page 349
container_title Journal of atmospheric chemistry
container_volume 16
creator Kames, J
Schurath, U
Flocke, F
Volz-Thomas, A
description The laboratory synthesis of mono- and bifunctional organic nitrates from the reaction of alcohols and dinitrogen pentoxide is described. The preparation of the organic nitrates was performed in an all-glass vacuum line with Teflon stopcocks to which three traps for N sub(2)O sub(5), alcohol, and the reaction products were attached. The experimental preparation of the organic nitrate products and the gas chromatographic analyses are described. Reaction yields were determined for methyl nitrate, ethyl nitrate, 2-propyl nitrate, 2-methyl-1-propyl nitrate, and nitrooxyacetone.
format article
fullrecord <record><control><sourceid>proquest</sourceid><recordid>TN_cdi_proquest_miscellaneous_18220184</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>14302113</sourcerecordid><originalsourceid>FETCH-LOGICAL-p934-a81a99a0a1568063890de97411265d3d9be111f638eaa706ca696314429e898b3</originalsourceid><addsrcrecordid>eNqFjL1qwzAURj200DTtO2gqzWDQlWRZGkPoTyDEgWQP1_Z1o2JbrmS_f03TPdOB7zucu2TBQedpnmv1kDzG-M05N8Lmi2Q8BBow4Oh8z3zDivCFvavY3o3zSJE1wXds3Vb-4tvIsK_ZnsWpfBWr4o_ZijU-sONAlZv1bU396BpXXYuuZ-ux83G4UJirR-yGluJTct9gG-n5n8vk9P522nymu-Jju1nv0sFKlaIBtBY5QqYN19JYXpPNFYDQWS1rWxIANPNBiDnXFWqrJSglLBlrSrlMXq7ZIfifieJ47lysqG2xJz_FMxghOBh1W9QZZFJkt0UluQCQ8hfRmnC9</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>14302113</pqid></control><display><type>article</type><title>Preparation of Organic Nitrates from Alcohols and N sub(2)O sub(5) for Species Identification in Atmospheric Samples</title><source>Springer Online Journal Archives</source><creator>Kames, J ; Schurath, U ; Flocke, F ; Volz-Thomas, A</creator><creatorcontrib>Kames, J ; Schurath, U ; Flocke, F ; Volz-Thomas, A</creatorcontrib><description>The laboratory synthesis of mono- and bifunctional organic nitrates from the reaction of alcohols and dinitrogen pentoxide is described. The preparation of the organic nitrates was performed in an all-glass vacuum line with Teflon stopcocks to which three traps for N sub(2)O sub(5), alcohol, and the reaction products were attached. The experimental preparation of the organic nitrate products and the gas chromatographic analyses are described. Reaction yields were determined for methyl nitrate, ethyl nitrate, 2-propyl nitrate, 2-methyl-1-propyl nitrate, and nitrooxyacetone.</description><identifier>ISSN: 0167-7764</identifier><language>eng</language><ispartof>Journal of atmospheric chemistry, 1993-01, Vol.16 (4), p.349-359</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780</link.rule.ids></links><search><creatorcontrib>Kames, J</creatorcontrib><creatorcontrib>Schurath, U</creatorcontrib><creatorcontrib>Flocke, F</creatorcontrib><creatorcontrib>Volz-Thomas, A</creatorcontrib><title>Preparation of Organic Nitrates from Alcohols and N sub(2)O sub(5) for Species Identification in Atmospheric Samples</title><title>Journal of atmospheric chemistry</title><description>The laboratory synthesis of mono- and bifunctional organic nitrates from the reaction of alcohols and dinitrogen pentoxide is described. The preparation of the organic nitrates was performed in an all-glass vacuum line with Teflon stopcocks to which three traps for N sub(2)O sub(5), alcohol, and the reaction products were attached. The experimental preparation of the organic nitrate products and the gas chromatographic analyses are described. Reaction yields were determined for methyl nitrate, ethyl nitrate, 2-propyl nitrate, 2-methyl-1-propyl nitrate, and nitrooxyacetone.</description><issn>0167-7764</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1993</creationdate><recordtype>article</recordtype><recordid>eNqFjL1qwzAURj200DTtO2gqzWDQlWRZGkPoTyDEgWQP1_Z1o2JbrmS_f03TPdOB7zucu2TBQedpnmv1kDzG-M05N8Lmi2Q8BBow4Oh8z3zDivCFvavY3o3zSJE1wXds3Vb-4tvIsK_ZnsWpfBWr4o_ZijU-sONAlZv1bU396BpXXYuuZ-ux83G4UJirR-yGluJTct9gG-n5n8vk9P522nymu-Jju1nv0sFKlaIBtBY5QqYN19JYXpPNFYDQWS1rWxIANPNBiDnXFWqrJSglLBlrSrlMXq7ZIfifieJ47lysqG2xJz_FMxghOBh1W9QZZFJkt0UluQCQ8hfRmnC9</recordid><startdate>19930101</startdate><enddate>19930101</enddate><creator>Kames, J</creator><creator>Schurath, U</creator><creator>Flocke, F</creator><creator>Volz-Thomas, A</creator><scope>7ST</scope><scope>C1K</scope><scope>SOI</scope><scope>7TV</scope><scope>7TG</scope><scope>KL.</scope></search><sort><creationdate>19930101</creationdate><title>Preparation of Organic Nitrates from Alcohols and N sub(2)O sub(5) for Species Identification in Atmospheric Samples</title><author>Kames, J ; Schurath, U ; Flocke, F ; Volz-Thomas, A</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-p934-a81a99a0a1568063890de97411265d3d9be111f638eaa706ca696314429e898b3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1993</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Kames, J</creatorcontrib><creatorcontrib>Schurath, U</creatorcontrib><creatorcontrib>Flocke, F</creatorcontrib><creatorcontrib>Volz-Thomas, A</creatorcontrib><collection>Environment Abstracts</collection><collection>Environmental Sciences and Pollution Management</collection><collection>Environment Abstracts</collection><collection>Pollution Abstracts</collection><collection>Meteorological &amp; Geoastrophysical Abstracts</collection><collection>Meteorological &amp; Geoastrophysical Abstracts - Academic</collection><jtitle>Journal of atmospheric chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Kames, J</au><au>Schurath, U</au><au>Flocke, F</au><au>Volz-Thomas, A</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Preparation of Organic Nitrates from Alcohols and N sub(2)O sub(5) for Species Identification in Atmospheric Samples</atitle><jtitle>Journal of atmospheric chemistry</jtitle><date>1993-01-01</date><risdate>1993</risdate><volume>16</volume><issue>4</issue><spage>349</spage><epage>359</epage><pages>349-359</pages><issn>0167-7764</issn><abstract>The laboratory synthesis of mono- and bifunctional organic nitrates from the reaction of alcohols and dinitrogen pentoxide is described. The preparation of the organic nitrates was performed in an all-glass vacuum line with Teflon stopcocks to which three traps for N sub(2)O sub(5), alcohol, and the reaction products were attached. The experimental preparation of the organic nitrate products and the gas chromatographic analyses are described. Reaction yields were determined for methyl nitrate, ethyl nitrate, 2-propyl nitrate, 2-methyl-1-propyl nitrate, and nitrooxyacetone.</abstract><tpages>11</tpages></addata></record>
fulltext fulltext
identifier ISSN: 0167-7764
ispartof Journal of atmospheric chemistry, 1993-01, Vol.16 (4), p.349-359
issn 0167-7764
language eng
recordid cdi_proquest_miscellaneous_18220184
source Springer Online Journal Archives
title Preparation of Organic Nitrates from Alcohols and N sub(2)O sub(5) for Species Identification in Atmospheric Samples
url http://sfxeu10.hosted.exlibrisgroup.com/loughborough?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-02-01T09%3A56%3A01IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Preparation%20of%20Organic%20Nitrates%20from%20Alcohols%20and%20N%20sub(2)O%20sub(5)%20for%20Species%20Identification%20in%20Atmospheric%20Samples&rft.jtitle=Journal%20of%20atmospheric%20chemistry&rft.au=Kames,%20J&rft.date=1993-01-01&rft.volume=16&rft.issue=4&rft.spage=349&rft.epage=359&rft.pages=349-359&rft.issn=0167-7764&rft_id=info:doi/&rft_dat=%3Cproquest%3E14302113%3C/proquest%3E%3Cgrp_id%3Ecdi_FETCH-LOGICAL-p934-a81a99a0a1568063890de97411265d3d9be111f638eaa706ca696314429e898b3%3C/grp_id%3E%3Coa%3E%3C/oa%3E%3Curl%3E%3C/url%3E&rft_id=info:oai/&rft_pqid=14302113&rft_id=info:pmid/&rfr_iscdi=true