Difference in α-thiocyanation of malonates, β-oxo esters and β-diketones with sodium thiocyanate and cerium(IV) ammonium nitrate

[Display omitted] β-Diketones and β-oxo esters are thiocyanated with the NaSCN/(NH4)2 Ce(NO3)6 system or with pre-generated dirhodanogen. Malonates undergo thiocyanation only with the NaSCN/(NH4)2 Ce(NO3)6 system.

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Bibliographic Details
Published in:Mendeleev communications 2016-05, Vol.26 (3), p.226-227
Main Authors: Terent’ev, Alexander O., Sharipov, Mikhail Yu, Glinuskin, Alexey P., Krylov, Igor B., Gaidarenko, Darya V., Nikishin, Gennady I.
Format: Article
Language:English
Subjects:
Ammonium nitrates
Esters
Sodium thiocyanate
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Description
Summary:[Display omitted] β-Diketones and β-oxo esters are thiocyanated with the NaSCN/(NH4)2 Ce(NO3)6 system or with pre-generated dirhodanogen. Malonates undergo thiocyanation only with the NaSCN/(NH4)2 Ce(NO3)6 system.
ISSN:0959-9436
DOI:10.1016/j.mencom.2016.05.001