Solution processed pristine PDPP3T polymer as hole transport layer for efficient perovskite solar cells with slower degradation

• Published in: Solar energy materials and solar cells 2016-02, Vol.145 (Part 3), p.193-199
• Main Authors: Dubey, Ashish, Adhikari, Nirmal, Venkatesan, Swaminathan, Gu, Shaopeng, Khatiwada, Devendra, Wang, Qi, Mohammad, Lal, Kumar, Mukesh, Qiao, Qiquan
• Format: Article
• Language: English
• Subjects: Acetonitrile; Degradation; Devices; Exposure; Hole transport layer; PDPP3T; Perovskite; Perovskites; Photovoltaic cells; Pristine polymer; Slower degradation; Solar cells; Transport
• ISSN: 0927-0248; 1879-3398
• DOI: 10.1016/j.solmat.2015.10.008

We report solution processed pristine diketopyrrolopyrrole (DPP) based polymer (PDPP3T) as hole transport layer (HTL) for perovskite (CH3NH3PbI3) solar cells. The pristine PDPP3T based perovskite solar cells achieved comparable photovoltaic performance (12.32%) as that (12.34%) of doped spiro-OMeTAD based cells. After exposing to air having 40% relative humidity at room temperature, PDPP3T based perovskite solar cells showed much slower degradation than spiro-OMeTAD cells. The PDPP3T based devices showed an efficiency decrease by 26.6% after being in air for 73h and 60.6% for 172h, while the spiro-OMeTAD cells exhibited a much larger efficiency decrease of 41.4% for 73h and 82.9% for 172h. The use of pristine PDPP3T does not require processing HTL in air and adding any additives such as lithium salt dissolved in acetonitrile, 4-tert-butylpyridine (TBP), which are needed for the spiro-OMeTAD HTL preparation. This prevents exposure of the perovskite layer to ambient air and avoids corrosion of perovskite layer by acetonitrile solvent and formation of PbI2.xTBP complex which leads to slow down the cell degradation and improves device stability. [Display omitted] •Solution processed pristine PDPP3T polymer was used as hole transport layer (HTL) to replace spiro-OMeTAD.•The PDPP3T based perovskite solar cells achieved comparable performance as doped spiro-OMeTAD based cells.•PDPP3T does not require processing HTL in air and avoid addition of any additives.•Polymer PDPP3T based solar cells showed slower degradation than spiro-OMeTAD based cells.