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All-thiolate-protected silver and silver-rich alloy nanoclusters with atomic precision: stable sizes, structural characterization and optical properties
Ultrasmall metal clusters (
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| Published in: | CrystEngComm 2016-01, Vol.18 (22), p.3996-45 |
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| Main Authors: | , , , |
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| cites | cdi_FETCH-LOGICAL-c286t-9f0f3982ceb01a4a85a5336428dc9c23edb56e43569638d2caf62b5b99916add3 |
| container_end_page | 45 |
| container_issue | 22 |
| container_start_page | 3996 |
| container_title | CrystEngComm |
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| creator | Jin, Renxi Zhao, Shuo Xing, Yan Jin, Rongchao |
| description | Ultrasmall metal clusters ( |
| doi_str_mv | 10.1039/c5ce02494c |
| format | article |
| fullrecord | <record><control><sourceid>proquest_rsc_p</sourceid><recordid>TN_cdi_proquest_miscellaneous_1825513847</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>1825513847</sourcerecordid><originalsourceid>FETCH-LOGICAL-c286t-9f0f3982ceb01a4a85a5336428dc9c23edb56e43569638d2caf62b5b99916add3</originalsourceid><addsrcrecordid>eNpNkU1v2zAMho2hBZamu-xewMehmFvJslSrt8BIP4ACvWxng6ZpRINieZK8Ifkl-7nVkm7tiV8P-RJkln3m7Iozoa9RIrGy0hV-yBa8UqqomRAn7_yP2VkIPxjjFedskf1ZWVvEjXEWIhWTd5EwUp8HY3-Rz2H85xbe4CYHa90uH2F0aOcQyYf8t4kpH93WYD55QhOMG2_zEKGzlJr3FL6myM8YZw82xw14SBre7CEm9KDhpmgwFdMCE_loKJxnpwPYQJ9e7TL7frf-1jwUT8_3j83qqcCyVrHQAxuErkukjnGooJYghVBVWfeosRTUd1JRJaTSStR9iTCospOd1por6HuxzL4c5ybpnzOF2G5NQLIWRnJzaHldSslFXd0k9PKIoncheBrayZst-F3LWfv3_G0jm_Xh_E2CL46wD_ife3uPeAEGxIZ4</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>1825513847</pqid></control><display><type>article</type><title>All-thiolate-protected silver and silver-rich alloy nanoclusters with atomic precision: stable sizes, structural characterization and optical properties</title><source>Royal Society of Chemistry Journals</source><creator>Jin, Renxi ; Zhao, Shuo ; Xing, Yan ; Jin, Rongchao</creator><creatorcontrib>Jin, Renxi ; Zhao, Shuo ; Xing, Yan ; Jin, Rongchao</creatorcontrib><description>Ultrasmall metal clusters (<2 nm), with dimensions between those of small molecules and plasmonic metal nanoparticles, have received significant attention due to their discrete electronic structure as well as unique physical and chemical properties. It remains to be a major dream for nanochemists to accomplish the controllable synthesis and structure analysis of clusters with atomic precision. This dream has been realized in gold clusters, especially all-thiolate (SR)-protected clusters. In contrast, despite the similarities between gold and silver, all-thiolate-protected silver clusters have been less reported due primarily to the low stability and synthetic bottlenecks. Nevertheless, there has been some success in Ag clusters recently. Since the total structure of [Ag
44
(SR)
30
]
4−
was solved by Bigioni's group and Zheng's group independently, a few more structures have been achieved including [Ag
25
(SR)
18
]
−
and [Ag
29
(SR)
12
(TPP)
4
]
3−
(TPP: triphenylphosphine) very recently. Moreover, some Ag-rich alloy clusters have also been reported, such as [MAg
24
(SR)
18
]
2−
(M = Pd, Pt), [AuAg
24
(SR)
18
]
−
, [Au
12
Ag
32
(SR)
30
]
4−
and [Ag
46
Au
24
(SR)
32
]
2+
. In this Highlight, some recent progress in developing strategies for the synthesis of high-quality all-thiolated Ag and Ag-rich alloy clusters will be emphasized. The stable sizes, structural characterization and optical properties will be discussed in detail. A brief outlook on the future development of Ag and Ag-rich alloy clusters from the viewpoint of controlled synthesis, stability enhancement and single-atom level manipulation will be given.
The stable sizes, structural characterization and optical properties of all-thiolate-protected silver and silver-rich alloy nanoclusters with atomic precision are highlighted.</description><identifier>ISSN: 1466-8033</identifier><identifier>EISSN: 1466-8033</identifier><identifier>DOI: 10.1039/c5ce02494c</identifier><language>eng</language><subject>Clusters ; Gold ; Nanostructure ; Optical properties ; Silver ; Silver base alloys ; Structural analysis ; Synthesis</subject><ispartof>CrystEngComm, 2016-01, Vol.18 (22), p.3996-45</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c286t-9f0f3982ceb01a4a85a5336428dc9c23edb56e43569638d2caf62b5b99916add3</citedby><cites>FETCH-LOGICAL-c286t-9f0f3982ceb01a4a85a5336428dc9c23edb56e43569638d2caf62b5b99916add3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27901,27902</link.rule.ids></links><search><creatorcontrib>Jin, Renxi</creatorcontrib><creatorcontrib>Zhao, Shuo</creatorcontrib><creatorcontrib>Xing, Yan</creatorcontrib><creatorcontrib>Jin, Rongchao</creatorcontrib><title>All-thiolate-protected silver and silver-rich alloy nanoclusters with atomic precision: stable sizes, structural characterization and optical properties</title><title>CrystEngComm</title><description>Ultrasmall metal clusters (<2 nm), with dimensions between those of small molecules and plasmonic metal nanoparticles, have received significant attention due to their discrete electronic structure as well as unique physical and chemical properties. It remains to be a major dream for nanochemists to accomplish the controllable synthesis and structure analysis of clusters with atomic precision. This dream has been realized in gold clusters, especially all-thiolate (SR)-protected clusters. In contrast, despite the similarities between gold and silver, all-thiolate-protected silver clusters have been less reported due primarily to the low stability and synthetic bottlenecks. Nevertheless, there has been some success in Ag clusters recently. Since the total structure of [Ag
44
(SR)
30
]
4−
was solved by Bigioni's group and Zheng's group independently, a few more structures have been achieved including [Ag
25
(SR)
18
]
−
and [Ag
29
(SR)
12
(TPP)
4
]
3−
(TPP: triphenylphosphine) very recently. Moreover, some Ag-rich alloy clusters have also been reported, such as [MAg
24
(SR)
18
]
2−
(M = Pd, Pt), [AuAg
24
(SR)
18
]
−
, [Au
12
Ag
32
(SR)
30
]
4−
and [Ag
46
Au
24
(SR)
32
]
2+
. In this Highlight, some recent progress in developing strategies for the synthesis of high-quality all-thiolated Ag and Ag-rich alloy clusters will be emphasized. The stable sizes, structural characterization and optical properties will be discussed in detail. A brief outlook on the future development of Ag and Ag-rich alloy clusters from the viewpoint of controlled synthesis, stability enhancement and single-atom level manipulation will be given.
The stable sizes, structural characterization and optical properties of all-thiolate-protected silver and silver-rich alloy nanoclusters with atomic precision are highlighted.</description><subject>Clusters</subject><subject>Gold</subject><subject>Nanostructure</subject><subject>Optical properties</subject><subject>Silver</subject><subject>Silver base alloys</subject><subject>Structural analysis</subject><subject>Synthesis</subject><issn>1466-8033</issn><issn>1466-8033</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2016</creationdate><recordtype>article</recordtype><recordid>eNpNkU1v2zAMho2hBZamu-xewMehmFvJslSrt8BIP4ACvWxng6ZpRINieZK8Ifkl-7nVkm7tiV8P-RJkln3m7Iozoa9RIrGy0hV-yBa8UqqomRAn7_yP2VkIPxjjFedskf1ZWVvEjXEWIhWTd5EwUp8HY3-Rz2H85xbe4CYHa90uH2F0aOcQyYf8t4kpH93WYD55QhOMG2_zEKGzlJr3FL6myM8YZw82xw14SBre7CEm9KDhpmgwFdMCE_loKJxnpwPYQJ9e7TL7frf-1jwUT8_3j83qqcCyVrHQAxuErkukjnGooJYghVBVWfeosRTUd1JRJaTSStR9iTCospOd1por6HuxzL4c5ybpnzOF2G5NQLIWRnJzaHldSslFXd0k9PKIoncheBrayZst-F3LWfv3_G0jm_Xh_E2CL46wD_ife3uPeAEGxIZ4</recordid><startdate>20160101</startdate><enddate>20160101</enddate><creator>Jin, Renxi</creator><creator>Zhao, Shuo</creator><creator>Xing, Yan</creator><creator>Jin, Rongchao</creator><scope>AAYXX</scope><scope>CITATION</scope><scope>7U5</scope><scope>8FD</scope><scope>L7M</scope></search><sort><creationdate>20160101</creationdate><title>All-thiolate-protected silver and silver-rich alloy nanoclusters with atomic precision: stable sizes, structural characterization and optical properties</title><author>Jin, Renxi ; Zhao, Shuo ; Xing, Yan ; Jin, Rongchao</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c286t-9f0f3982ceb01a4a85a5336428dc9c23edb56e43569638d2caf62b5b99916add3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2016</creationdate><topic>Clusters</topic><topic>Gold</topic><topic>Nanostructure</topic><topic>Optical properties</topic><topic>Silver</topic><topic>Silver base alloys</topic><topic>Structural analysis</topic><topic>Synthesis</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Jin, Renxi</creatorcontrib><creatorcontrib>Zhao, Shuo</creatorcontrib><creatorcontrib>Xing, Yan</creatorcontrib><creatorcontrib>Jin, Rongchao</creatorcontrib><collection>CrossRef</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Technology Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>CrystEngComm</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Jin, Renxi</au><au>Zhao, Shuo</au><au>Xing, Yan</au><au>Jin, Rongchao</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>All-thiolate-protected silver and silver-rich alloy nanoclusters with atomic precision: stable sizes, structural characterization and optical properties</atitle><jtitle>CrystEngComm</jtitle><date>2016-01-01</date><risdate>2016</risdate><volume>18</volume><issue>22</issue><spage>3996</spage><epage>45</epage><pages>3996-45</pages><issn>1466-8033</issn><eissn>1466-8033</eissn><abstract>Ultrasmall metal clusters (<2 nm), with dimensions between those of small molecules and plasmonic metal nanoparticles, have received significant attention due to their discrete electronic structure as well as unique physical and chemical properties. It remains to be a major dream for nanochemists to accomplish the controllable synthesis and structure analysis of clusters with atomic precision. This dream has been realized in gold clusters, especially all-thiolate (SR)-protected clusters. In contrast, despite the similarities between gold and silver, all-thiolate-protected silver clusters have been less reported due primarily to the low stability and synthetic bottlenecks. Nevertheless, there has been some success in Ag clusters recently. Since the total structure of [Ag
44
(SR)
30
]
4−
was solved by Bigioni's group and Zheng's group independently, a few more structures have been achieved including [Ag
25
(SR)
18
]
−
and [Ag
29
(SR)
12
(TPP)
4
]
3−
(TPP: triphenylphosphine) very recently. Moreover, some Ag-rich alloy clusters have also been reported, such as [MAg
24
(SR)
18
]
2−
(M = Pd, Pt), [AuAg
24
(SR)
18
]
−
, [Au
12
Ag
32
(SR)
30
]
4−
and [Ag
46
Au
24
(SR)
32
]
2+
. In this Highlight, some recent progress in developing strategies for the synthesis of high-quality all-thiolated Ag and Ag-rich alloy clusters will be emphasized. The stable sizes, structural characterization and optical properties will be discussed in detail. A brief outlook on the future development of Ag and Ag-rich alloy clusters from the viewpoint of controlled synthesis, stability enhancement and single-atom level manipulation will be given.
The stable sizes, structural characterization and optical properties of all-thiolate-protected silver and silver-rich alloy nanoclusters with atomic precision are highlighted.</abstract><doi>10.1039/c5ce02494c</doi><tpages>1</tpages></addata></record> |
| fulltext | fulltext |
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| ispartof | CrystEngComm, 2016-01, Vol.18 (22), p.3996-45 |
| issn | 1466-8033 1466-8033 |
| language | eng |
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| source | Royal Society of Chemistry Journals |
| subjects | Clusters Gold Nanostructure Optical properties Silver Silver base alloys Structural analysis Synthesis |
| title | All-thiolate-protected silver and silver-rich alloy nanoclusters with atomic precision: stable sizes, structural characterization and optical properties |
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