Microwave absorption properties of polypyrrole-SrFe12O19-TiO2-epoxy resin nanocomposites: Optimization using response surface methodology

• Published in: Applied surface science 2016-10, Vol.383, p.9-18
• Main Authors: Seyed Dorraji, M.S., Rasoulifard, M.H., Amani-Ghadim, A.R., Khodabandeloo, M.H., Felekari, M., Khoshrou, M.R., hajimiri, I.
• Format: Article
• Language: English
• Subjects: Dielectric; Mathematical models; Microwave absorption; Nanocomposites; Nanostructure; Optimization; Organic-inorganic composite; Radar wave absorption; Reflection loss; Response surface methodology; Titanium dioxide; X-band
• ISSN: 0169-4332; 1873-5584
• DOI: 10.1016/j.apsusc.2016.04.108

[Display omitted] •Polypyrrole-SrFe12O19-TiO2-epoxy resin nanocomposite was prepared.•Response surface methodology was used to optimize the microwaves absorption.•The sample prepared in optimal condition had reflection loss lower than −15dB. At a few works are discussed about formation of heterogeneous composites with different distribution of particle shape and size that are used for electromagnetic absorption purposes. In this study a novel heterogeneous nanocpmposites is investigated. The nanocomposite has been successfully prepared based on epoxy resin including various nano-metal oxides (TiO2, SrFe12O19) and polypyrrole (PPy) by sol-gel and the solution chemistry method, respectively. The performance of prepared nanocomposite in absorption of microwave in X-band range was investigated and transmission line method by X-band waveguide straight was used to measure EM parameters of nanocomposites. The Response surface methodology (RSM) with central composite design (CCD) was utilized to study the effects of the wt.% TiO2 in SrFe12O19, wt.% Tio2-SrFe12O19 in PPy and wt.% TiO2-SrFe12O19-PPy in epoxy resin, on the microwave absorption properties with the absorber thickness of only 2mm. The proposed quadratic model was in accordance with the experimental results with correlation coefficient of 96.5%. The optimum condition for maximum microwave absorption efficiency were wt.% TiO2 in SrFe12O19 of 70, wt.% TiO2-SrFe12O19 in PPy of 10 and wt.% TiO2-SrFe12O19-PPy in epoxy of 25. The sample prepared in optimal conditions indicated reflection loss of −15dB corresponding to 97% absorption, at the range of 9.2–10.8GHz.