Morphology and mesopores in photoelectrochemically active LaTiO sub(2)N single crystals

The mesoporous network within photocatalytically and photoelectrochemically active LaTiO sub(2)N (LTON) single crystals was investigated by electron microscopy techniques including electron diffraction and scanning transmission electron microscopy imaging. The perovskite-related oxynitride particles...

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Bibliographic Details
Published in:Journal of materials research 2016-06, Vol.31 (11), p.1574-1579
Main Authors: Pokrant, Simone, Dilger, Stefan, Landsmann, Steve
Format: Article
Language:English
Subjects:
Ammonolysis
Imaging
Micrometers
Oxynitrides
Pore formation
Porosity
Single crystals
Transformations
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Summary:The mesoporous network within photocatalytically and photoelectrochemically active LaTiO sub(2)N (LTON) single crystals was investigated by electron microscopy techniques including electron diffraction and scanning transmission electron microscopy imaging. The perovskite-related oxynitride particles were obtained by thermal ammonolysis from monocrystalline micrometer-sized La sub(2)Ti sub(2)O sub(7) (LTO) particles grown by flux-assisted solid state synthesis. Special attention was paid to the crystal transformation from the monoclinic layered LTO to the orthorhombic perovskite-related LTON within the monocrystalline particles. A detailed analysis of pore directions and pore sizes with respect to the LTON particle shape was performed. The pore formation mechanism taking place during thermal ammonolysis was discussed. Based on the mechanistic understanding of the transformation from the oxide to the oxynitride, a further extension of the mesoporous network toward higher surface areas was proposed for improved photoelectrochemical activity of oxynitride particles, while high crystallinity and particle sizes in the micrometer range continue to enable efficient charge transport.
ISSN:0884-2914
2044-5326
DOI:10.1557/jmr.2016.9